The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Synergistic Assembly of Heavy Metal Clusters and Luminescent Organic Bridging Ligands in Metal–Organic Frameworks for Highly Efficient X-ray Scintillation
Open accessAbstract
We have designed two metal-organic frameworks (MOFs) to efficiently convert X-ray to visible-light luminescence. The MOFs are constructed from M6(μ3-O)4(μ3-OH)4(carboxylate)12 (M = Hf or Zr) secondary building units (SBUs) and anthracene-based dicarboxylate bridging ligands. The high atomic number of Zr and Hf in the SBUs serves as effective X-ray antenna by absorbing X-ray photons and converting them to fast electrons through the photoelectric effect. The generated electrons then excite multiple anthracene-based emitters in the MOF through inelastic scattering, leading to efficient generation of detectable photons in the visible spectrum. The MOF materials thus serve as efficient X-ray scintillators via synergistic X-ray absorption by the metal-cluster SBUs and optical emission by the bridging ligands.
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Metadata
- Authors
- Wang, C., Volotskova, O., Lu, K., Ahmad, M., Sun, C., Xing, L., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-16
- Volume
- 136
- Issue
- 17
- Pages
- 6171-6174
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2327712306
- Cited by
- 283
- References
- 29
- FWCI
- 5.93
- Type
- journal article
- Language
- en
- Open access
- hybrid
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