The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Facile Synthesis of Z-Alkenes via Uphill Catalysis
Abstract
Catalytic access to thermodynamically less stable Z-alkenes has recently received considerable attention. These approaches have relied upon kinetic control of the reaction to arrive at the thermodynamically less stable geometrical isomer. Herein, we present an orthogonal approach which proceeds via photochemically catalyzed isomerization of the thermodynamic E-alkene to the less stable Z-isomer which occurs via a photochemical pumping mechanism. We consider two potential mechanisms. Importantly, the reaction conditions are mild, tolerant, and operationally simple and will be easily implemented.
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Cites
Ein neuer Katalysator für selektive Hydrierungen
Lindlar, H. (1952) · Helvetica Chimica Acta · doi:10.1002/hlca.19520350205 · Cited by 1,168
Mechanisms of Photochemical Reactions in Solution. XXII.1 Photochemical cis-trans Isomerization
Hammond, G. S., Saltiel, J., Lamola, A. A., Turro, N. J., Bradshaw, J. S., Cowan, D. O., Counsell, R. C., Vogt, V., & Dalton, C. (1964) · Journal of the American Chemical Society · doi:10.1021/ja01070a002 · Cited by 542
Visible Light Photocatalysis of [2+2] Styrene Cycloadditions by Energy Transfer
Lu, Z., & Yoon, T. P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204835 · Cited by 415
Freeman, D. B., Furst, L., Condie, A. G., & Stephenson, C. R. J. (2012) · Organic Letters · doi:10.1021/ol202883v · Cited by 388
Designing systems for one-way trans to cis photoisomerization for solar reactions
Zhao, Y., Yang, L., & Liu, R. S. H. (2009) · Green Chemistry · doi:10.1039/b819207c · Cited by 26
Cited by
The Hitchhiker’s Guide to Flow Chemistry
Plutschack, M. B., Pieber, B., Gilmore, K., & Seeberger, P. H. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00183 · Cited by 1,995
Cambié, D., Bottecchia, C., Straathof, N. J. W., Hessel, V., & Noël, T. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00707 · Cited by 1,502
Visible‐Light‐Induced Organic Photochemical Reactions through Energy‐Transfer Pathways
Zhou, Q., Zou, Y., Lu, L., & Xiao, W. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201803102 · Cited by 1,156
Triplet Energy Transfer Photocatalysis: Unlocking the Next Level
Strieth-Kalthoff, F., & Glorius, F. (2020) · Chem · doi:10.1016/j.chempr.2020.07.010 · Cited by 650
Teegardin, K., Day, J. I., Chan, J., & Weaver, J. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00101 · Cited by 593
Self-citation
Metadata
- Authors
- Singh, K., Staig, S. J., & Weaver, J. D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-28
- Volume
- 136
- Issue
- 14
- Pages
- 5275-5278
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2318185398
- Cited by
- 396
- References
- 5
- FWCI
- 9.11
- Type
- journal article
- Language
- en
- Open access
- closed
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