The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Hydrated Manganese(II) Phosphate (Mn3(PO4)2·3H2O) as a Water Oxidation Catalyst
Abstract
The development of a water oxidation catalyst has been a demanding challenge in realizing water splitting systems. The asymmetric geometry and flexible ligation of the biological Mn4CaO5 cluster are important properties for the function of photosystem II, and these properties can be applied to the design of new inorganic water oxidation catalysts. We identified a new crystal structure, Mn3(PO4)2·3H2O, that precipitates spontaneously in aqueous solution at room temperature and demonstrated its high catalytic performance under neutral conditions. The bulky phosphate polyhedron induces a less-ordered Mn geometry in Mn3(PO4)2·3H2O. Computational analysis indicated that the structural flexibility in Mn3(PO4)2·3H2O could stabilize the Jahn-Teller-distorted Mn(III) and thus facilitate Mn(II) oxidation. This study provides valuable insights into the interplay between atomic structure and catalytic activity.
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Cites
Grätzel, M. (2001) · Nature · doi:10.1038/35104607 · Cited by 12,687
Powering the planet: Chemical challenges in solar energy utilization
Lewis, N. S., & Nocera, D. G. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0603395103 · Cited by 8,310
Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries
Padhi, A. K., Nanjundaswamy, K. S., & Goodenough, J. B. (1997) · Journal of The Electrochemical Society · doi:10.1149/1.1837571 · Cited by 7,933
In Situ Formation of an Oxygen-Evolving Catalyst in Neutral Water Containing Phosphate and Co 2+
Kanan, M. W., & Nocera, D. G. (2008) · Science · doi:10.1126/science.1162018 · Cited by 4,122
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
Umena, Y., Kawakami, K., Shen, J.-R., & Kamiya, N. (2011) · Nature · doi:10.1038/nature09913 · Cited by 3,913
Architecture of the Photosynthetic Oxygen-Evolving Center
Ferreira, K. N., Iverson, T. M., Maghlaoui, K., Barber, J., & Iwata, S. (2004) · Science · doi:10.1126/science.1093087 · Cited by 3,329
Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen
Bard, A. J., & Fox, M. A. (1995) · Accounts of Chemical Research · doi:10.1021/ar00051a007 · Cited by 2,577
Solar Fuels via Artificial Photosynthesis
Gust, D., Moore, T. A., & Moore, A. L. (2009) · Accounts of Chemical Research · doi:10.1021/ar900209b · Cited by 2,063
Towards complete cofactor arrangement in the 3.0 Å resolution structure of photosystem II
Loll, B., Kern, J., Saenger, W., Zouni, A., & Biesiadka, J. (2005) · Nature · doi:10.1038/nature04224 · Cited by 1,867
Photosynthetic energy conversion: natural and artificial
Barber, J. (2009) · Chem. Soc. Rev. · doi:10.1039/b802262n · Cited by 1,843
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Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Zhu, Y., Zhou, W., Yu, J., Chen, Y., Liu, M., & Shao, Z. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04457 · Cited by 845
Lu, X., Gu, L., Wang, J., Wu, J., Liao, P., & Li, G. (2017) · Advanced Materials · doi:10.1002/adma.201604437 · Cited by 784
Indra, A., Menezes, P. W., Sahraie, N. R., Bergmann, A., Das, C., Tallarida, M., Schmeißer, D., Strasser, P., & Driess, M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja509348t · Cited by 666
Liu, X., Meng, J., Zhu, J., Huang, M., Wen, B., Guo, R., & Mai, L. (2021) · Advanced Materials · doi:10.1002/adma.202007344 · Cited by 438
Li, Y., & Zhao, C. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03497 · Cited by 346
Li, J., Wei, G., Zhu, Y., Xi, Y., Pan, X., Ji, Y., Zatovsky, I. V., & Han, W. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta03947f · Cited by 309
Sun, S., Sun, Y., Zhou, Y., Shen, J., Mandler, D., Neumann, R., & Xu, Z. J. (2019) · Chemistry of Materials · doi:10.1021/acs.chemmater.9b02737 · Cited by 137
Strong Metal Phosphide–Phosphate Support Interaction for Enhanced Non‐Noble Metal Catalysis
Chen, Z., Zeng, X., Li, X., Lv, Z., Li, J., & Zhang, Y. (2022) · Advanced Materials · doi:10.1002/adma.202106724 · Cited by 98
Metadata
- Authors
- Jin, K., Park, J., Lee, J., Yang, K. D., Pradhan, G. K., Sim, U., Jeong, D., Jang, H. L., Park, S., Kim, D., Sung, N.-E., Kim, S. H., Han, S., & Nam, K. T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-07
- Volume
- 136
- Issue
- 20
- Pages
- 7435-7443
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1974064298
- Cited by
- 377
- References
- 39
- FWCI
- 10.92
- Type
- journal article
- Language
- en
- Open access
- closed
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