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Single-Particle Study of Pt-Modified Au Nanorods for Plasmon-Enhanced Hydrogen Generation in Visible to Near-Infrared Region
Abstract
Pt-modified Au nanorods (NRs) synthesized by anisotropic overgrowth were used for producing H2 under visible and near-infrared light irradiation. The Pt-tipped sample exhibited much higher activity compared with fully covered samples. Using single-particle spectroscopies combined with transmission electron microscopy, we observed obvious quenching phenomena for photoluminescence and light scattering from individual Pt-tipped NRs. The analysis of energy relaxation of plasmon-generated hot electrons indicates the electron transfer from the excited Au to Pt.
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Metadata
- Authors
- Zheng, Z., Tachikawa, T., & Majima, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-02
- Volume
- 136
- Issue
- 19
- Pages
- 6870-6873
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2326043749
- Cited by
- 473
- References
- 24
- FWCI
- 13.86
- Type
- journal article
- Language
- en
- Open access
- closed
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