The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Ordered Mesoporous Black TiO2 as Highly Efficient Hydrogen Evolution Photocatalyst
Abstract
Mesoporous TiO2 has gained increasing interest because of its outstanding properties and promising applications in a wide range of fields. Herein, we report the facile synthesis of ordered mesoporous black TiO2 (OMBT) materials, which exhibit excellent photocatalytic hydrogen evolution performances. In this case, the employment of a thermally stable and high-surface-area mesoporous TiO2 as the hydrogenation precursor is the key for fabricating the OMBT materials, which not only facilitate H2 gas diffusion into TiO2 and interaction with their structures but also maintain the ordered mesoporous structures as well as inhibit the phase transformation (from anatase to rutile) and crystal growth during hydrogenation at 500 °C. The resultant OMBT materials possess a relatively high surface area of ∼124 m(2) g(-1) and a large pore size and pore volume of ∼9.6 nm and 0.24 cm(3) g(-1), respectively. More importantly, the OMBT materials can extend the photoresponse from ultraviolet to visible and infrared light regions and exhibit a high solar-driven hydrogen production rate (136.2 μmol h(-1)), which is almost two times as high as that of pristine mesoporous TiO2 (76.6 μmol h(-1)).
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Cites
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1998) · Nature · doi:10.1038/24132 · Cited by 2,493
Self-citationMesoporous Anatase Titania Hollow Nanostructures though Silica‐Protected Calcination
Joo, J. B., Zhang, Q., Lee, I., Dahl, M., Zaera, F., & Yin, Y. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201101927 · Cited by 433
Cited by
Recent advances in floating TiO2-based photocatalysts for environmental application
Xing, Z., Zhang, J., Cui, J., Yin, J., Zhao, T., Kuang, J., Xiu, Z., Wan, N., & Zhou, W. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.12.005 · Cited by 550
Self-citationLi, C., Li, Q., Kaneti, Y. V., Hou, D., Yamauchi, Y., & Mai, Y. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00021c · Cited by 513
Liu, X., Xing, Z., Zhang, Y., Li, Z., Wu, X., Tan, S., Yu, X., Zhu, Q., & Zhou, W. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.08.031 · Cited by 367
Self-citationFull‐Spectrum Solar‐Light‐Activated Photocatalysts for Light–Chemical Energy Conversion
Wang, X., Wang, F., Sang, Y., & Liu, H. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700473 · Cited by 328
Chen, X., Zhao, D., Liu, K., Wang, C., Liu, L., Li, B., Zhang, Z., & Shen, D. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b04568 · Cited by 147
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Metadata
- Authors
- Zhou, W., Li, W., Wang, J.-Q., Qu, Y., Yang, Y., Xie, Y., Zhang, K., Wang, L., Fu, H., & Zhao, D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-23
- Volume
- 136
- Issue
- 26
- Pages
- 9280-9283
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2326940845
- Cited by
- 980
- References
- 2
- FWCI
- 27.62
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, W., Li, W., Wang, J.-Q., Qu, Y., Yang, Y., Xie, Y., Zhang, K., Wang, L., Fu, H., & Zhao, D. (2014). Ordered Mesoporous Black TiO2 as Highly Efficient Hydrogen Evolution Photocatalyst. Journal of the American Chemical Society. https://doi.org/10.1021/ja504802q
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