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Cited by 357

The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.

A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity

Open access
Lü, Jian, Perez-Krap, Cristina, Suyetin, Mikhail, Alsmail, Nada H., Yan, Yong, Yang, Sihai, Lewis, William, Bichoutskaia, Elena, Tang, Chiu C., Blake, Alexander J., Cao, Rong, Schröder, Martin·2014·Journal of the American Chemical Society

Abstract

A robust binary hydrogen-bonded supramolecular organic framework (SOF-7) has been synthesized by solvothermal reaction of 1,4-bis-(4-(3,5-dicyano-2,6-dipyridyl)dihydropyridyl)benzene (1) and 5,5'-bis-(azanediyl)-oxalyl-diisophthalic acid (2). Single crystal X-ray diffraction analysis shows that SOF-7 comprises 2 and 1,4-bis-(4-(3,5-dicyano-2,6-dipyridyl)pyridyl)benzene (3); the latter formed in situ from the oxidative dehydrogenation of 1. SOF-7 shows a three-dimensional four-fold interpenetrated structure with complementary O-H···N hydrogen bonds to form channels that are decorated with cyano and amide groups. SOF-7 exhibits excellent thermal stability and solvent and moisture durability as well as permanent porosity. The activated desolvated material SOF-7a shows high CO2 adsorption capacity and selectivity compared with other porous organic materials assembled solely through hydrogen bonding.

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Metadata

Authors
Lü, J., Perez-Krap, C., Suyetin, M., Alsmail, N. H., Yan, Y., Yang, S., Lewis, W., Bichoutskaia, E., Tang, C. C., Blake, A. J., Cao, R., & Schröder, M.
Venue
Journal of the American Chemical Society
Published
2014-09-03
Volume
136
Issue
37
Pages
12828-12831
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1968993426
Cited by
357
References
3
FWCI
14.15
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity. https://app.cochat.ai/papers/10.1021/ja506577g
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Lü, J., Perez-Krap, C., Suyetin, M., Alsmail, N. H., Yan, Y., Yang, S., Lewis, W., Bichoutskaia, E., Tang, C. C., Blake, A. J., Cao, R., & Schröder, M. (2014). A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity. Journal of the American Chemical Society. https://doi.org/10.1021/ja506577g

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