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Cited by 211

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Photodissociation of B–N Lewis Adducts: A Partially Fused Trinaphthylborane with Dual Fluorescence

Matsuo, Kyohei, Saito, Shohei, Yamaguchi, Shigehiro·2014·Journal of the American Chemical Society

Abstract

The synthesis of a planarized trinaphthylborane with partially fused structure is presented. This compound shows not only high chemical and thermal stability but also sufficient Lewis acidity to form Lewis adducts with pyridine derivatives in solution. The B-N Lewis adducts exhibit unprecedented photodissociation behavior in the excited state, reminiscent of the photogeneration of carbenium ions from triarylmethane leuco dyes. Consequently, these B-N Lewis adducts exhibit dual fluorescence emission arising from the initial tetracoordinate B-N adducts and the photodissociated tricoordinate boranes.

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Metadata

Authors
Matsuo, K., Saito, S., & Yamaguchi, S.
Venue
Journal of the American Chemical Society
Published
2014-08-29
Volume
136
Issue
36
Pages
12580-12583
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2319551386
Cited by
211
References
1
FWCI
8.09
Type
journal article
Language
en
Open access
closed

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