The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Proton Conductivity Control by Ion Substitution in a Highly Proton-Conductive Metal–Organic Framework
Abstract
Proton conductivity through two-dimensional (2-D) hydrogen-bonding networks within a layered metal-organic framework (MOF) (NH4)2(H2adp)[Zn2(ox)3]·3H2O (H2adp = adipic acid; ox = oxalate) has been successfully controlled by cation substitution. We synthesized a cation-substituted MOF, K2(H2adp)[Zn2(ox)3]·3H2O, where the ammonium ions in a well-defined hydrogen-bonding network are substituted with non-hydrogen-bonding potassium ions, without any apparent change in the crystal structure. We successfully controlled the proton conductivity by cleavage of the hydrogen bonds in a proton-conducting pathway, showing that the 2-D hydrogen-bonding networks in the MOF truly contribute to the high proton conductivity. This is the first example of the control of proton conductivity by ion substitution in a well-defined hydrogen-bonding network within a MOF.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Cited by
Applications of water stable metal–organic frameworks
Wang, C., Liu, X., Keser Demir, N., Chen, J. P., & Li, K. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00362a · Cited by 1,249
Hydrogen-Bonded Organic Frameworks as a Tunable Platform for Functional Materials
Wang, B., Lin, R.-B., Zhang, Z., Xiang, S., & Chen, B. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06473 · Cited by 852
Proton-conducting crystalline porous materials
Meng, X., Wang, H.-N., Song, S.-Y., & Zhang, H.-J. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00528d · Cited by 697
Proton Transport in Metal–Organic Frameworks
Lim, D.-W., & Kitagawa, H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00842 · Cited by 689
Self-citationMetal‐Organic Framework‐Based Nanomaterials for Electrocatalysis
Mahmood, A., Guo, W., Tabassum, H., & Zou, R. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600423 · Cited by 632
Karmakar, A., Illathvalappil, R., Anothumakkool, B., Sen, A., Samanta, P., Desai, A. V., Kurungot, S., & Ghosh, S. K. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604534 · Cited by 517
Li, W.-H., Deng, W.-H., Wang, G.-E., & Xu, G. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100029 · Cited by 373
Metadata
- Authors
- Sadakiyo, M., Yamada, T., & Kitagawa, H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-09-16
- Volume
- 136
- Issue
- 38
- Pages
- 13166-13169
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2319784678
- Cited by
- 229
- References
- 2
- FWCI
- 10.16
- Type
- journal article
- Language
- en
- Open access
- closed
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