The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Salicylaldimine-Based Metal–Organic Framework Enabling Highly Active Olefin Hydrogenation with Iron and Cobalt Catalysts
Abstract
A robust and porous Zr metal-organic framework, sal-MOF, of UiO topology was synthesized using a salicylaldimine (sal)-derived dicarboxylate bridging ligand. Postsynthetic metalation of sal-MOF with iron(II) or cobalt(II) chloride followed by treatment with NaBEt3H in THF resulted in Fe- and Co-functionalized MOFs (sal-M-MOF, M = Fe, Co) which are highly active solid catalysts for alkene hydrogenation. Impressively, sal-Fe-MOF displayed very high turnover numbers of up to 145000 and was recycled and reused more than 15 times. This work highlights the unique opportunity of developing MOF-based earth-abundant catalysts for sustainable chemical synthesis.
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Citations
Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Cited by
Liu, X., Zhou, Y., Zhang, J., Tang, L., Luo, L., & Zeng, G. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b02563 · Cited by 312
Metadata
- Authors
- Manna, K., Zhang, T., Carboni, M., Abney, C. W., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-09-15
- Volume
- 136
- Issue
- 38
- Pages
- 13182-13185
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1964451037
- Cited by
- 171
- References
- 1
- FWCI
- 11.29
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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