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Monitoring the Solid-State Electrochemistry of Cu(2,7-AQDC) (AQDC = Anthraquinone Dicarboxylate) in a Lithium Battery: Coexistence of Metal and Ligand Redox Activities in a Metal–Organic Framework
Abstract
By adopting a facile synthetic strategy, we obtained a microporous redox-active metal-organic framework (MOF), namely, Cu(2,7-AQDC) (2,7-H2AQDC = 2,7-anthraquinonedicarboxylic acid) (1), and utilized it as a cathode active material in lithium batteries. With a voltage window of 4.0-1.7 V, both metal clusters and anthraquinone groups in the ligands exhibited reversible redox activity. The valence change of copper cations was clearly evidenced by in situ XANES analysis. By controlling the voltage window of operation, extremely high recyclability of batteries was achieved, suggesting the framework was robust. This MOF is the first example of a porous material showing independent redox activity on both metal cluster nodes and ligand sites.
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Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
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Wang, H., Zhu, Q.-L., Zou, R., & Xu, Q. (2017) · Chem · doi:10.1016/j.chempr.2016.12.002 · Cited by 1,200
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Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
Liu, J., & Wöll, C. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00315c · Cited by 698
Nam, K. W., Park, S. S., dos Reis, R., Dravid, V. P., Kim, H., Mirkin, C. A., & Stoddart, J. F. (2019) · Nature Communications · doi:10.1038/s41467-019-12857-4 · Cited by 688
Metadata
- Authors
- Zhang, Z., Yoshikawa, H., & Awaga, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-10
- Volume
- 136
- Issue
- 46
- Pages
- 16112-16115
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2318050461
- Cited by
- 315
- References
- 1
- FWCI
- 11.01
- Type
- journal article
- Language
- en
- Open access
- closed
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