The DOI matches its Crossref record.
Dissolution and Liquid Crystals Phase of 2D Polymeric Carbon Nitride
Abstract
Graphite-phase polymeric carbon nitride (GPPCN) has emerged as a promising metal-free material toward optoelectronics and (photo)catalysis. However, the insolubility of GPPCN remains one of the biggest impediments toward its potential applications. Herein, we report that GPPCN could be dissolved in concentrated sulfuric acid, the first feasible solvent so far, due to the synergistic protonation and intercalation. The concentration was up to 300 mg/mL, thousands of time higher than previous reported dispersions. As a result, the first successful liquid-state NMR spectra of GPPCN were obtained, which provides a more feasible method to reveal the finer structure of GPPCN. Moreover, at high concentration, a liquid crystal phase for the carbon nitride family was first observed. The successful dissolution of GPPCN and the formation of highly anisotropic mesophases would greatly pave the potential applications such as GPPCN-based nanocomposites or assembly of marcroscopic, ordered materials.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
2D Graphitic Carbon Nitride for Energy Conversion and Storage
Wang, Y., Liu, L., Ma, T., Zhang, Y., & Huang, H. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202102540 · Cited by 448
Self-citationLi, H., Gan, S., Wang, H., Han, D., & Niu, L. (2015) · Advanced Materials · doi:10.1002/adma.201502755 · Cited by 339
Linker-controlled polymeric photocatalyst for highly efficient hydrogen evolution from water
Wang, Y., Bayazit, M. K., Moniz, S. J. A., Ruan, Q., Lau, C. C., Martsinovich, N., & Tang, J. (2017) · Energy & Environmental Science · doi:10.1039/c7ee01109a · Cited by 258
Xu, Y., & Zhang, B. (2015) · Catalysis Science & Technology · doi:10.1039/c5cy00365b · Cited by 43
Metadata
- Authors
- Zhou, Z., Wang, J., Yu, J., Shen, Y., Li, Y., Liu, A., Liu, S., & Zhang, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-04
- Volume
- 137
- Issue
- 6
- Pages
- 2179-2182
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2318805091
- Cited by
- 333
- References
- 0
- FWCI
- 12.32
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Dissolution and Liquid Crystals Phase of 2D Polymeric Carbon Nitride. https://app.cochat.ai/papers/10.1021/ja512179x
- The paper
- Zhou, Z., Wang, J., Yu, J., Shen, Y., Li, Y., Liu, A., Liu, S., & Zhang, Y. (2015). Dissolution and Liquid Crystals Phase of 2D Polymeric Carbon Nitride. Journal of the American Chemical Society. https://doi.org/10.1021/ja512179x
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
