The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds: Mass-Spectrometric Determination of Molecular Formulas and Structural Implications
Abstract
The molecular formulas and charge state distributions of thus-far known ubiquitous alkanethiolate-protected gold clusters with core-masses of 8 and 29 kDa were assessed using electrospray ionization mass spectrometry. The 8 and 29 kDa clusters were determined to be composed of single species, [Au38(SCn)24]z and [Au144(SCn)59]z, respectively, with charge states of z >/= 0. Possible geometric structures for Au38(SCn)24 and Au144(SCn)59 are discussed, based on the structures of relevant systems that have been recently determined experimentally and theoretically: [Au25(SR)18]- and Au102(SR)44, in which the Au cores are protected by monomers [-SR-Au-SR-] and/or dimers [-SR-Au-SR-Au-SR-]. Their preferential formation and chemical robustness are proposed as being associated with high stability due to geometric factors, while the Au-thiolate interface takes on common motifs regardless of the underlying Au core.
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Cites
Formation and Structure of Self-Assembled Monolayers
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Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system
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Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties
Zhu, M., Aikens, C. M., Hollander, F. J., Schatz, G. C., & Jin, R. (2008) · Journal of the American Chemical Society · doi:10.1021/ja801173r · Cited by 2,348
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Self-citationCrystal Structure of the Gold Nanoparticle [N(C 8 H 17 ) 4 ][Au 25 (SCH 2 CH 2 Ph) 18 ]
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On the Structure of Thiolate-Protected Au25
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Cited by
Quantum sized, thiolate-protected gold nanoclusters
Jin, R. (2010) · Nanoscale · doi:10.1039/b9nr00160c · Cited by 1,442
Atomically precise metal nanoclusters: stable sizes and optical properties
Jin, R. (2015) · Nanoscale · doi:10.1039/c4nr05794e · Cited by 867
Different sized luminescent gold nanoparticles
Zheng, J., Zhou, C., Yu, M., & Liu, J. (2012) · Nanoscale · doi:10.1039/c2nr31192e · Cited by 600
Enhancement in Aerobic Alcohol Oxidation Catalysis of Au25 Clusters by Single Pd Atom Doping
Xie, S., Tsunoyama, H., Kurashige, W., Negishi, Y., & Tsukuda, T. (2012) · ACS Catalysis · doi:10.1021/cs300252g · Cited by 403
Self-citationUnraveling the long-pursued Au 144 structure by x-ray crystallography
Yan, N., Xia, N., Liao, L., Zhu, M., Jin, F., Jin, R., & Wu, Z. (2018) · Science Advances · doi:10.1126/sciadv.aat7259 · Cited by 353
Metadata
- Authors
- Chaki, N. K., Negishi, Y., Tsunoyama, H., Shichibu, Y., & Tsukuda, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-06-12
- Volume
- 130
- Issue
- 27
- Pages
- 8608-8610
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2029510139
- Cited by
- 393
- References
- 35
- FWCI
- 15.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Chaki, N. K., Negishi, Y., Tsunoyama, H., Shichibu, Y., & Tsukuda, T. (2008). Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds: Mass-Spectrometric Determination of Molecular Formulas and Structural Implications. Journal of the American Chemical Society. https://doi.org/10.1021/ja8005379
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