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Reversible Mechanochromic Luminescence of [(C6F5Au)2(μ-1,4-Diisocyanobenzene)]
Abstract
Reversible mechanochromic luminescence of [(C6F5Au)2(mu-1,4-diisocyanobenzene)] is reported. Grinding of the complex induced a photoluminescent color change, which was restored by exposure to a solvent. This cycle was repeated 20 times with no color degradation in the emissions. Their optical properties, X-ray crystallographic analysis, IR, and XRD measurements strongly suggested that the change in the molecular arrangement is responsible for this mechanochromic property. Intermolecular aurophilic bondings presumably play a key role in the altered emission.
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Cited by
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Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Hong, Y., Lam, J. W. Y., & Tang, B. Z. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15113d · Cited by 6,363
Recent advances in mechanochromic luminescent metal complexes
Zhang, X., Chi, Z., Zhang, Y., Liu, S., & Xu, J. (2013) · Journal of Materials Chemistry C · doi:10.1039/c3tc30316k · Cited by 632
Yuan, W. Z., Tan, Y., Gong, Y., Lu, P., Lam, J. W. Y., Shen, X. Y., Feng, C., Sung, H. H., Lu, Y., Williams, I. D., et al. (2013) · Advanced Materials · doi:10.1002/adma.201205043 · Cited by 470
Metadata
- Authors
- Ito, H., Saito, T., Oshima, N., Kitamura, N., Ishizaka, S., Hinatsu, Y., Wakeshima, M., Kato, M., Tsuge, K., & Sawamura, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-07-10
- Volume
- 130
- Issue
- 31
- Pages
- 10044-10045
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2089158509
- Cited by
- 625
- References
- 0
- FWCI
- 10.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ito, H., Saito, T., Oshima, N., Kitamura, N., Ishizaka, S., Hinatsu, Y., Wakeshima, M., Kato, M., Tsuge, K., & Sawamura, M. (2008). Reversible Mechanochromic Luminescence of [(C6F5Au)2(μ-1,4-Diisocyanobenzene)]. Journal of the American Chemical Society. https://doi.org/10.1021/ja8019356
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