The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Order−Disorder Antiferroelectric Phase Transition in a Hybrid Inorganic−Organic Framework with the Perovskite Architecture
Abstract
[(CH3)2NH2]Zn(HCOO)3, 1, adopts a structure that is analogous to that of a traditional perovskite, ABX3, with A = [(CH3)2NH2], B = Zn, and X = HCOO. The hydrogen atoms of the dimethyl ammonium cation, which hydrogen bond to oxygen atoms of the formate framework, are disordered at room temperature. X-ray powder diffraction, dielectric constant, and specific heat data show that 1 undergoes an order-disorder phase transition on cooling below 156 K. We present evidence that this is a classical paraelectric to antiferroelectric phase transition that is driven by ordering of the hydrogen atoms. This sort of electrical ordering associated with order-disorder phase transition is unprecedented in hybrid frameworks and opens up an exciting new direction in rational synthetic strategies to create extended hybrid networks for applications in ferroic-related fields.
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Cites
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Self-citationHybrid inorganic–organic materials: a new family in condensed matter physics
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Self-citationBridging phases at the morphotropic boundaries of lead oxide solid solutions
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Cited by
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Ferroelectric Metal–Organic Frameworks
Zhang, W., & Xiong, R.-G. (2012) · Chemical Reviews · doi:10.1021/cr200174w · Cited by 1,378
Metal-free three-dimensional perovskite ferroelectrics
Ye, H.-Y., Tang, Y.-Y., Li, P.-F., Liao, W.-Q., Gao, J.-X., Hua, X.-N., Cai, H., Shi, P.-P., You, Y.-M., & Xiong, R.-G. (2018) · Science · doi:10.1126/science.aas9330 · Cited by 814
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Self-citationTayi, A. S., Kaeser, A., Matsumoto, M., Aida, T., & Stupp, S. I. (2015) · Nature Chemistry · doi:10.1038/nchem.2206 · Cited by 474
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Metal–organic framework structures – how closely are they related to classical inorganic structures?
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Myths and reality of HPbI3 in halide perovskite solar cells
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How Strong Is the Hydrogen Bond in Hybrid Perovskites?
Svane, K. L., Forse, A. C., Grey, C. P., Kieslich, G., Cheetham, A. K., Walsh, A., & Butler, K. T. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b03106 · Cited by 256
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Metadata
- Authors
- Jain, P., Dalal, N. S., Toby, B. H., Kroto, H. W., & Cheetham, A. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-07-18
- Volume
- 130
- Issue
- 32
- Pages
- 10450-10451
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2089556499
- Cited by
- 489
- References
- 12
- FWCI
- 9.94
- Type
- journal article
- Language
- en
- Open access
- closed
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