The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Analysis of the Concerted Metalation-Deprotonation Mechanism in Palladium-Catalyzed Direct Arylation Across a Broad Range of Aromatic Substrates
Abstract
The concerted metalation-deprotonation mechanism predicts relative reactivity and regioselectivity for a diverse set of arenes spanning the entire spectrum of known palladium-catalyzed direct arylation coupling partners. An analysis following an active strain model provides a more complete portrayal of the important arene/catalyst parameters leading to a successful coupling. The breadth of arenes whose reactivity can be predicted by the CMD mechanism indicates that it may be far more widespread than previously imagined.
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Citations
Cites
Density-functional thermochemistry. III. The role of exact exchange
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464913 · Cited by 103,767
Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
Cited by
Cho, S. H., Kim, J. Y., Kwak, J., & Chang, S. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15082k · Cited by 2,358
Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations
Ackermann, L. (2014) · Accounts of Chemical Research · doi:10.1021/ar3002798 · Cited by 1,640
Gorelsky, S. I., Lapointe, D., & Fagnou, K. (2012) · The Journal of Organic Chemistry · doi:10.1021/jo202342q · Cited by 438
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Metadata
- Authors
- Gorelsky, S. I., Lapointe, D., & Fagnou, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-07-29
- Volume
- 130
- Issue
- 33
- Pages
- 10848-10849
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1980934047
- Cited by
- 1,009
- References
- 2
- FWCI
- 31.53
- Type
- journal article
- Language
- en
- Open access
- closed
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