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Synthesis of CuInS2, CuInSe2, and Cu(InxGa1-x)Se2(CIGS) Nanocrystal “Inks” for Printable Photovoltaics
Abstract
Chalcopyrite copper indium sulfide (CuInS2) and copper indium gallium selenide (Cu(InxGa(1-x))-Se2; CIGS) nanocrystals ranging from approximately 5 to approximately 25 nm in diameter were synthesized by arrested precipitation in solution. The In/Ga ratio in the CIGS nanocrystals could be controlled by varying the In/Ga reactant ratio in the reaction, and the optical properties of the CulnS2 and CIGS nanocrystals correspond to those of the respective bulk materials. Using methods developed to produce uniform, crack-free micrometer-thick films, CulnSe2 nanocrystals were tested in prototype photovoltaic devices. As a proof-of-concept, the nanocrystal-based devices exhibited a reproducible photovoltaic response.
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Cited by
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Habas, S. E., Platt, H. A. S., van Hest, M. F. A. M., & Ginley, D. S. (2010) · Chemical Reviews · doi:10.1021/cr100191d · Cited by 459
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Metadata
- Authors
- Panthani, M. G., Akhavan, V., Goodfellow, B., Schmidtke, J. P., Dunn, L., Dodabalapur, A., Barbara, P. F., & Korgel, B. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-11-17
- Volume
- 130
- Issue
- 49
- Pages
- 16770-16777
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2016316384
- Cited by
- 927
- References
- 0
- FWCI
- 52.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Panthani, M. G., Akhavan, V., Goodfellow, B., Schmidtke, J. P., Dunn, L., Dodabalapur, A., Barbara, P. F., & Korgel, B. A. (2008). Synthesis of CuInS2, CuInSe2, and Cu(InxGa1-x)Se2(CIGS) Nanocrystal “Inks” for Printable Photovoltaics. Journal of the American Chemical Society. https://doi.org/10.1021/ja805845q
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