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Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds
Abstract
A Pd(II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The reaction conditions are also applicable for the carboxylation of vinyl C-H bonds. The first C-H insertion Pd-aryl complex from carboxylic acids has been characterized by X-ray crystallography.
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Citations
Cited by
Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions
Engle, K. M., Mei, T.-S., Wasa, M., & Yu, J.-Q. (2012) · Accounts of Chemical Research · doi:10.1021/ar200185g · Cited by 2,716
Self-citationTransition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups
Chen, Z., Wang, B., Zhang, J., Yu, W., Liu, Z., & Zhang, Y. (2015) · Organic Chemistry Frontiers · doi:10.1039/c5qo00004a · Cited by 1,533
Transition-Metal-Catalyzed C–H Bond Activation for the Formation of C–C Bonds in Complex Molecules
Docherty, J. H., Lister, T. M., Mcarthur, G., Findlay, M. T., Domingo-Legarda, P., Kenyon, J., Choudhary, S., & Larrosa, I. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00888 · Cited by 593
Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
Liu, B., Romine, A. M., Rubel, C. Z., Engle, K. M., & Shi, B.-F. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00519 · Cited by 538
Engle, K. M., & Yu, J.-Q. (2013) · The Journal of Organic Chemistry · doi:10.1021/jo400159y · Cited by 531
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Metadata
- Authors
- Giri, R., & Yu, J.-Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-10-04
- Volume
- 130
- Issue
- 43
- Pages
- 14082-14083
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2083044747
- Cited by
- 378
- References
- 0
- FWCI
- 15.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds. https://app.cochat.ai/papers/10.1021/ja8063827
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- Giri, R., & Yu, J.-Q. (2008). Synthesis of 1,2- and 1,3-Dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of Aryl and Vinyl C−H Bonds. Journal of the American Chemical Society. https://doi.org/10.1021/ja8063827
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