The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis
Abstract
Au clusters smaller than 1.5 nm and stabilized by poly(N-vinyl-2-pyrrolidone) (PVP) showed higher activity for aerobic oxidation of alcohol than those of larger size or stabilized by poly(allylamine) (PAA). X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy of adsorbed CO, and X-ray absorption near edge structure measurements revealed that the catalytically active Au clusters are negatively charged by electron donation from PVP, and the catalytic activity is enhanced with increasing electron density on the Au core. Based on similar observations of Au cluster anions in the gas phase, we propose that electron transfer from the anionic Au cores of Au:PVP into the LUMO (pi*) of O(2) generates superoxo- or peroxo-like species, which plays a key role in the oxidation of alcohol. On the basis of these results, a simple principle is presented for the synthesis of Au oxidation catalysts stabilized by organic molecules.
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Cites
Supported gold nanoparticles as catalysts for organic reactions
Corma, A., & Garcia, H. (2008) · Chemical Society Reviews · doi:10.1039/b707314n · Cited by 1,883
Charging Effects on Bonding and Catalyzed Oxidation of CO on Au 8 Clusters on MgO
Yoon, B., Häkkinen, H., Landman, U., Wörz, A. S., Antonietti, J.-M., Abbet, S., Judai, K., & Heiz, U. (2005) · Science · doi:10.1126/science.1104168 · Cited by 1,430
Narayanan, R., & El-Sayed, M. A. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp051066p · Cited by 1,298
Cited by
Quantum sized, thiolate-protected gold nanoclusters
Jin, R. (2010) · Nanoscale · doi:10.1039/b9nr00160c · Cited by 1,442
Catalytic Organic Reactions in Water toward Sustainable Society
Kitanosono, T., Masuda, K., Xu, P., & Kobayashi, S. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00417 · Cited by 770
Nonscalable Oxidation Catalysis of Gold Clusters
Yamazoe, S., Koyasu, K., & Tsukuda, T. (2014) · Accounts of Chemical Research · doi:10.1021/ar400209a · Cited by 607
Self-citationRole of the Support in Gold-Containing Nanoparticles as Heterogeneous Catalysts
Sankar, M., He, Q., Engel, R. V., Sainna, M. A., Logsdail, A. J., Roldan, A., Willock, D. J., Agarwal, N., Kiely, C. J., & Hutchings, G. J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00662 · Cited by 485
Nanostructured Catalysts for Organic Transformations
Chng, L. L., Erathodiyil, N., & Ying, J. Y. (2013) · Accounts of Chemical Research · doi:10.1021/ar300197s · Cited by 450
Metadata
- Authors
- Tsunoyama, H., Ichikuni, N., Sakurai, H., & Tsukuda, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-05-01
- Volume
- 131
- Issue
- 20
- Pages
- 7086-7093
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2029777289
- Cited by
- 670
- References
- 3
- FWCI
- 21.37
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tsunoyama, H., Ichikuni, N., Sakurai, H., & Tsukuda, T. (2009). Effect of Electronic Structures of Au Clusters Stabilized by Poly(N-vinyl-2-pyrrolidone) on Aerobic Oxidation Catalysis. Journal of the American Chemical Society. https://doi.org/10.1021/ja810045y
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