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Cited by 1,387

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties

Liang, Yongye, Feng, Danqin, Wu, Yue, Tsai, Szu-Ting, Li, Gang, Ray, Claire, Yu, Luping·2009·Journal of the American Chemical Society

Abstract

This paper describes synthesis and photovoltaic studies of a series of new semiconducting polymers with alternating thieno[3,4-b]thiophene and benzodithiophene units. The physical properties of these polymers were finely tuned to optimize their photovoltaic effect. The substitution of alkoxy side chains to the less electron-donating alkyl chains or introduction of electron-withdrawing fluorine into the polymer backbone reduced the HOMO energy levels of polymers. The structural modifications optimized polymers' spectral coverage of absorption and their hole mobility, as well as miscibility with fulleride, and enhanced polymer solar cell performances. The open circuit voltage, V(oc), for polymer solar cells was increased by adjusting polymer energy levels. It was found that films with finely distributed polymer/fulleride interpenetrating network exhibited improved solar cell conversion efficiency. Efficiency over 6% has been achieved in simple solar cells based on fluorinated PTB4/PC(61)BM films prepared from mixed solvents. The results proved that polymer solar cells have a bright future.

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Metadata

Authors
Liang, Y., Feng, D., Wu, Y., Tsai, S.-T., Li, G., Ray, C., & Yu, L.
Venue
Journal of the American Chemical Society
Published
2009-05-19
Volume
131
Issue
22
Pages
7792-7799
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1988984118
Cited by
1,387
References
2
FWCI
135.96
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties. https://app.cochat.ai/papers/10.1021/ja901545q
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Liang, Y., Feng, D., Wu, Y., Tsai, S.-T., Li, G., Ray, C., & Yu, L. (2009). Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties. Journal of the American Chemical Society. https://doi.org/10.1021/ja901545q

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