The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties
Abstract
This paper describes synthesis and photovoltaic studies of a series of new semiconducting polymers with alternating thieno[3,4-b]thiophene and benzodithiophene units. The physical properties of these polymers were finely tuned to optimize their photovoltaic effect. The substitution of alkoxy side chains to the less electron-donating alkyl chains or introduction of electron-withdrawing fluorine into the polymer backbone reduced the HOMO energy levels of polymers. The structural modifications optimized polymers' spectral coverage of absorption and their hole mobility, as well as miscibility with fulleride, and enhanced polymer solar cell performances. The open circuit voltage, V(oc), for polymer solar cells was increased by adjusting polymer energy levels. It was found that films with finely distributed polymer/fulleride interpenetrating network exhibited improved solar cell conversion efficiency. Efficiency over 6% has been achieved in simple solar cells based on fluorinated PTB4/PC(61)BM films prepared from mixed solvents. The results proved that polymer solar cells have a bright future.
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Citations
Cites
Conjugated Polymer-Based Organic Solar Cells
Günes, S., Neugebauer, H., & Sariciftci, N. S. (2007) · Chemical Reviews · doi:10.1021/cr050149z · Cited by 6,279
Electrical characteristics and efficiency of single-layer organic light-emitting diodes
Malliaras, G. G., Salem, J. R., Brock, P. J., & Scott, C. (1998) · Physical Review B · doi:10.1103/physrevb.58.r13411 · Cited by 663
Cited by
A polymer tandem solar cell with 10.6% power conversion efficiency
You, J., Dou, L., Yoshimura, K., Kato, T., Ohya, K., Moriarty, T., Emery, K., Chen, C.-C., Gao, J., Li, G., et al. (2013) · Nature Communications · doi:10.1038/ncomms2411 · Cited by 2,778
Self-citationHe, Z., Zhong, C., Huang, X., Wong, W., Wu, H., Chen, L., Su, S., & Cao, Y. (2011) · Advanced Materials · doi:10.1002/adma.201103006 · Cited by 2,134
Li, S., Ye, L., Zhao, W., Zhang, S., Mukherjee, S., Ade, H., & Hou, J. (2016) · Advanced Materials · doi:10.1002/adma.201602776 · Cited by 1,380
Designing π-conjugated polymers for organic electronics
Guo, X., Baumgarten, M., & Müllen, K. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.09.005 · Cited by 836
Coffin, R. C., Peet, J., Rogers, J., & Bazan, G. C. (2009) · Nature Chemistry · doi:10.1038/nchem.403 · Cited by 597
Metadata
- Authors
- Liang, Y., Feng, D., Wu, Y., Tsai, S.-T., Li, G., Ray, C., & Yu, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-05-19
- Volume
- 131
- Issue
- 22
- Pages
- 7792-7799
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1988984118
- Cited by
- 1,387
- References
- 2
- FWCI
- 135.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liang, Y., Feng, D., Wu, Y., Tsai, S.-T., Li, G., Ray, C., & Yu, L. (2009). Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties. Journal of the American Chemical Society. https://doi.org/10.1021/ja901545q
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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