Band Gap Control in Conjugated Oligomers via Lewis Acids

Hard and Soft Acids and Bases

Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475

Design Rules for Donors in Bulk‐Heterojunction Solar Cells—Towards 10 % Energy‐Conversion Efficiency

Scharber, M., Mühlbacher, D., Koppe, M., Denk, P., Waldauf, C., Heeger, A. J., & Brabec, C. J. (2006) · Advanced Materials · doi:10.1002/adma.200501717 · Cited by 5,198

Dye-Sensitized Solar Cells

Grätzel, M. (2003) · Journal of Photochemistry and Photobiology C: Photochemistry Reviews · doi:10.1016/s1389-5567(03)00026-1 · Cited by 4,405

Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing

Kim, J. Y., Lee, K., Coates, N. E., Moses, D. J., Nguyen, T., Dante, M., & Heeger, A. J. (2007) · Science · doi:10.1126/science.1141711 · Cited by 3,270

Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols

Peet, J., Kim, J. Y., Coates, N. E., L., W., Moses, D. J., Heeger, A. J., & Bazan, G. C. (2007) · Nature Materials · doi:10.1038/nmat1928 · Cited by 3,203

Polymer‐Fullerene Bulk‐Heterojunction Solar Cells

Dennler, G., Scharber, M. C., & Brabec, C. J. (2009) · Advanced Materials · doi:10.1002/adma.200801283 · Cited by 3,161

Synthesis, Characterization, and Photovoltaic Properties of a Low Band Gap Polymer Based on Silole-Containing Polythiophenes and 2,1,3-Benzothiadiazole

Hou, J., Chen, H.-Y., Zhang, S., Li, G., & Yang, Y. (2008) · Journal of the American Chemical Society · doi:10.1021/ja806687u · Cited by 1,126

Molecular Engineering of the Band Gap of π‐Conjugated Systems: Facing Technological Applications

Roncali, J. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200700345 · Cited by 722

Lewis Acid Properties of Tris(pentafluorophenyl)borane. Structure and Bonding in L−B(C6F5)3 Complexes

Jacobsen, H., Berke, H., Döring, S., Kehr, G., Erker, G., Fröhlich, R., & Meyer, O. G. J. (1999) · Organometallics · doi:10.1021/om981033e · Cited by 359

Novel 2,1,3‐Benzothiadiazole‐Based Red‐Fluorescent Dyes with Enhanced Two‐Photon Absorption Cross‐Sections

Kato, S., Matsumoto, T., Shigeiwa, M., Gorohmaru, H., Maeda, S., Ishi‐i, T., & Mataka, S. (2005) · Chemistry - A European Journal · doi:10.1002/chem.200500921 · Cited by 244

Synthesis and photophysical properties of imine borane adducts towards vapochromic materials

Soltani, Y., Adams, S. J., Börger, J., Wilkins, L. C., Newman, P. D., Pope, S. J. A., & Melen, R. L. (2018) · Dalton Transactions · doi:10.1039/c8dt03019g · Cited by 17

Polytellurophenes with Properties Controlled by Tellurium‐Coordination

Jahnke, A. A., Howe, G. W., & Seferos, D. S. (2010) · Angewandte Chemie · doi:10.1002/ange.201005664 · Cited by 17

B ← N Coordination Enables Efficient p-Doping in a Pyrazine-Based Polymer Donor Toward Enhanced Photovoltaic Performance

Guo, L., Liu, K., Tan, X., Wang, X.-L., Huang, J., Wei, Z., & Chen, G. (2021) · Macromolecules · doi:10.1021/acs.macromol.1c01793 · Cited by 16

Synthesis of Conjugated Polymers Containing DIBAC-Derived Triazole Monomers

Chadwick, R. C., Kardelis, V., Liogier, S., & Adronov, A. (2013) · Macromolecules · doi:10.1021/ma4021467 · Cited by 16

Halochromic Switch from the 1st to 2nd Near-Infrared Window of Diazapentalene–Dithienosilole Copolymers

Khelifi, W., Awada, H., Brymora, K., Blanc, S. P.-L., Hirsch, L., Castet, F., Bousquet, A., & Lartigau‐Dagron, C. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b00675 · Cited by 15

N–C chelated tetraaryl-pyrazole based organoboranes: A new class of aggregation induced enhanced emission materials

Sa, S., Sahoo, A., Mukherjee, S., Perumal, A. K., & Venkatasubbaiah, K. (2022) · Dyes and Pigments · doi:10.1016/j.dyepig.2022.110585 · Cited by 15

Two Synthetic Approaches from 2,5-Di(2-thienyl)pyridine to a BF3-modified Polymer Film

Hayashi, S., & Koizumi, T. (2012) · Chemistry Letters · doi:10.1246/cl.2012.979 · Cited by 15

Erzeugung von Festkörperlumineszenz durch Koordination der Lewis‐Säure B(C6F5)3 an nicht‐emittierende Aldehyde

Hansmann, M. M., López‐Andarias, A., Rettenmeier, E., Egler‐Lucas, C., Röminger, F., Hashmi, A. S. K., & Romero‐Nieto, C. (2015) · Angewandte Chemie · doi:10.1002/ange.201508461 · Cited by 14

Discovery of the Quinoxalinone–B(C 6 F 5 ) 3 ·H 2 O Combo as a Photocatalyst by Acidochromism Strategy: Aerobic Oxidation of Alcohol, Alkene, and Thiols

Huang, J., Luo, Y.-X., Wang, L., & Tang, X. (2023) · Organic Letters · doi:10.1021/acs.orglett.3c01977 · Cited by 14

Protonation induced shifting of electron-accepting centers in intramolecular charge transfer chromophores: a theoretical study

Tang, T., Chi, H., Lin, T., Wang, F., & He, C. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp02410a · Cited by 14

Heli(aza)cene: A Helical Molecular Tweezer with Tunable Intra‐ and Intermolecular Charge Transfer

Kumar, R., Semwal, S., Choudhury, J., & Srivastava, A. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201703781 · Cited by 14

Twofold C−H Activation Enables Synthesis of a Diazacoronene‐Type Fluorophore with Near Infrared Emission Through Isosteric Replacement

Greßies, S., Ito, M., Sakai, M., Osaki, H., Kim, J. H., Gensch, T., Daniliuc, C. G., Ando, N., Yamaguchi, S., & Glorius, F. (2020) · Chemistry - A European Journal · doi:10.1002/chem.202004080 · Cited by 13

A versatile scaffold for facile synthesis of fluorescent cyano-substituted stilbenes

Hayashi, S., Sakamoto, M., Ishiwari, F., Fukushima, T., Yamamoto, S., & Koizumi, T. (2019) · Tetrahedron · doi:10.1016/j.tet.2019.01.012 · Cited by 13

Dispersion of Fullerene in Neat Synthesized Liquid-state Oligo(p-phenyleneethynylene)s

Adachi, N., Itagaki, R., Sugeno, M., & Norioka, T. (2014) · Chemistry Letters · doi:10.1246/cl.140587 · Cited by 12

Structure–property relationships of acylated asymmetric dithienophospholes

Gordon, T. J., Szabo, L. D., Linder, T., Berlinguette, C. P., & Baumgartner, T. (2010) · Comptes Rendus Chimie · doi:10.1016/j.crci.2010.04.023 · Cited by 12

Tris(pentafluorophenyl)borane‐pyrrolo[3,2‐b]pyrrole Hybrids: Solid‐State Structure and Crystallization‐Induced Enhanced Emission

Hatanaka, S., Ono, T., Yano, Y., Gryko, D. T., & Hisaeda, Y. (2019) · ChemPhotoChem · doi:10.1002/cptc.201900192 · Cited by 12

Post-synthesis of Lewis acid-base adducts as thermally activated delayed fluorescence radical emitters for color-tunable displays and encryption via inkjet printing

Liu, H., Tang, Y., Ying, A., Gao, Y., Chen, X., Zhou, L., Lin, J., & Xie, G. (2022) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.136642 · Cited by 11

Interaction of 1,3,2,4‐Benzodithiadiazines with Aromatic Phosphines and Phosphites

Grayfer, T., Makarov, A. Y., Bagryanskaya, I. Y., Irtegova, I. G., Gatilov, Y. V., & Zibarev, A. V. (2014) · Heteroatom Chemistry · doi:10.1002/hc.21209 · Cited by 11

The Electronic Spectra of the Sandwich Stacked PFBT: A Theoretical Study

Wang, J., Gu, J., & Leszczyński, J. (2011) · The Journal of Physical Chemistry A · doi:10.1021/jp201145q · Cited by 11

Complexation of B(C6F5)3 and 9,10-Dicyanoanthracene: Dual Role of Borane as Spatial and Electronic Tuner

Imagawa, T., Nakamoto, M., Shang, R., Adachi, Y., Ohshita, J., Tsunoji, N., & Yamamoto, Y. (2020) · Chemistry Letters · doi:10.1246/cl.200339 · Cited by 10

1,2,5-Thiadiazoles

Rakitin, O. A. (2020) · Elsevier eBooks · doi:10.1016/b978-0-12-409547-2.14813-9 · Cited by 9

Modulating electronic properties of dinitrosoarene polymers

Matasović, L., Panić, B., Bubaš, M., Vančik, H., Biljan, I., & Rončević, I. (2022) · Journal of Materials Chemistry C · doi:10.1039/d2tc00760f · Cited by 9

A Thermally Populated Germylene‐Based Donor‐Acceptor Diradical

Zhao, Y., Zhang, Y., Wang, T., Pei, R., Zhao, Y. C., Xue, X., & Wang, X. (2024) · Angewandte Chemie International Edition · doi:10.1002/anie.202411180 · Cited by 8

Revisiting the Fluorescence of Benzothiadiazole Derivatives: Anti‐Kasha Emission or Not?

Veys, K., de Jong, F., Adriaens, A., Coenen, G., Coenen, K., Ligt, Y. D., Meysman, Q., Paredis, T., Stalmans, J., Dehaen, W., et al. (2022) · ChemPhotoChem · doi:10.1002/cptc.202200262 · Cited by 8

Trifluoroacetic acid prompted unexpected visible to NIR switching of ketoenamine-substituted triphenylamines

Kandala, L. V. K., Che, Y., Raj, K. A., Perepichka, D. F., & Rao, M. R. (2023) · Journal of Materials Chemistry C · doi:10.1039/d2tc04959g · Cited by 8

Metal‐Free Catalytic Formation of a Donor‐Acceptor‐Donor Molecule and Its Lewis Acid‐Adduct Singlet Diradical with High‐Efficient NIR‐II Photothermal Conversion

Kong, S., Yang, L., Sun, Q., Wang, T., Pei, R., Zhao, Y. C., Wang, W., Zhao, Y., Cui, H., Gu, X., et al. (2024) · Angewandte Chemie · doi:10.1002/ange.202400913 · Cited by 8

Donor–Acceptor-Type Low Bandgap Polymer Carrying Phenylazomethine Moiety as a Metal-Collecting Pendant Unit: Open-Circuit Voltage Modulation of Solution-Processed Organic Photovoltaic Devices Induced by Metal Complexation

Kimoto, A., & Tajima, Y. (2012) · ACS Macro Letters · doi:10.1021/mz3001379 · Cited by 8

An acceptor-quantity modulation strategy for high-performance ambipolar semiconducting polymers: from a dual-acceptor to a quad-acceptor backbone

Jiao, K., Zuo, X., Shen, T., Li, W., Zhao, Y. J., Mo, X., Wang, Y., & Liu, Y. (2024) · Journal of Materials Chemistry C · doi:10.1039/d4tc01542h · Cited by 7

Synthetic Study of Novel π-Electron Materials Containing Boron, Nitrogen, and Phosphorus as Key Main Group Elements

Yamaguchi, S., & Fukazawa, A. (2011) · Journal of Synthetic Organic Chemistry Japan · doi:10.5059/yukigoseikyokaishi.69.661 · Cited by 7

Microscopic Insight into the Electronic Structure of BCF-Doped Oligothiophenes from Ab Initio Many-Body Theory

Schier, R., Valencia, A. M., & Cocchi, C. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c03124 · Cited by 7

Synergistic effect of hydrogen bonds and π-π interactions of B(C6F5)3·H2O/amides complex: Application in photoredox catalysis

Wang, S., Wang, L., & Tang, X. (2023) · iScience · doi:10.1016/j.isci.2023.106528 · Cited by 7

Doping-induced decomposition of organic semiconductors: a caveat to the use of Lewis acid p-dopants

Rotas, G., Antoniou, G., Papagiorgis, P. G., Basu, A., Panidi, J., Ufimkin, P., Tsetseris, L., Itskos, G., Heeney, M., Vougioukalakis, G. C., et al. (2022) · Journal of Materials Chemistry C · doi:10.1039/d2tc03048a · Cited by 7

Synergistic p-Doping of Polymer-Wrapped Small-Diameter Single-Walled Carbon Nanotubes by Tris(pentafluorophenyl)borane

Lindenthal, S., Rippel, D., Kistner, L., Hawkey, A., & Zaumseil, J. (2025) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.4c08584 · Cited by 6

Preparation of Solid-state Luminescent Materials by Complexation between π-Conjugated Molecules and Activators

Yamakawa, T., Yoshigoe, Y., Wang, Z., Kanai, M., & Kuninobu, Y. (2018) · Chemistry Letters · doi:10.1246/cl.180735 · Cited by 6

Novel high band gap pendant-borylated carbazole polymers with deep HOMO levels through direct + NB − interaction for organic photovoltaics

Brandt, R. G., Sveegaard, S. G., Xiao, M., Yue, W., Du, Z., Qiu, M., Angmo, D., Andersen, T. R., Krebs, F. C., Yang, R., et al. (2016) · Journal of Materials Chemistry C · doi:10.1039/c6tc01208f · Cited by 6

Quantum Chemistry–Machine Learning Approach for Predicting Properties of Lewis Acid–Lewis Base Adducts

Huynh, H., Kelly, T. J., Vu, L., Hoang, T., Nguyen, P. A., Le, T. C., Jarvis, E., & Phan, H. (2023) · ACS Omega · doi:10.1021/acsomega.3c02822 · Cited by 6

Post-synthesis from Lewis acid–base interaction: an alternative way to generate light and harvest triplet excitons

Liu, H., & Xie, G. (2022) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.18.83 · Cited by 6

Inorganic and organometallic polymers

Rivard, E. (2010) · Annual Reports Section A (Inorganic Chemistry) · doi:10.1039/b918405h · Cited by 6

Benzothiadiazole‐Based Diarylamines as a Fluoride Sensor: Prevention of Fluoride Induced Decomposition of Receptor Molecule by Complex Formation with Cu 2+

Elavarasan, K., Saravanan, C., Selvam, N. P., & Easwaramoorthi, S. (2018) · ChemistrySelect · doi:10.1002/slct.201801581 · Cited by 5

Tris(pentafluorophenyl)borane: leveraging historical and emerging work to identify alternatives for organic electronic applications

Wolfe, K. M., Grant, M. J., Park, I. E., & Welch, G. C. (2025) · New Journal of Chemistry · doi:10.1039/d5nj01430a · Cited by 4

Influences of donor/acceptor ratio on the optical and electrical properties of the D/A alternating model oligomers: A density functional theory study

Zheng, H., Zhao, Y., Song, M., Wang, J., Chen, L., Sun, L., & Bai, F. (2018) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2018.03.067 · Cited by 3

Writing and Erasing Encryption Information Based on Frustrated Lewis Pair Chemistry

Fang, H., Long, X., Lan, X., Ren, B., & Xie, G. (2023) · Precision Chemistry · doi:10.1021/prechem.3c00062 · Cited by 2

Soluble and highly fluorescent conjugated polymer network: non-oxidative reversible doping, cell imaging and anticancer activity

Gupta, N., Maity, S., Anamika, A., Behere, R. P., Mahata, P., Maiti, B., Maiti, P., & Kuila, B. K. (2023) · New Journal of Chemistry · doi:10.1039/d2nj06254b · Cited by 2

Conformational Effect on the Excitonic States of 2-Phenylpyridine Oligomers: Ab Initio Studies and Analysis

Mandal, P., & Panda, A. N. (2023) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.3c03601 · Cited by 1

Modification of Lewis Basic ^|^pi;-Conjugated Polymer Films via Br^|^oslash;nsted and Lewis Acid Vapor Treatments

Hayashi, S., ASANO, A., & Koizumi, T. (2014) · KOBUNSHI RONBUNSHU · doi:10.1295/koron.71.382 · Cited by 1

Effects of chemical dopants on the luminescence, bandgap and electrochemical conductivity of the thiophene-based benzothiadiazole-conjugated polymers

Karpagam, S., Anupriya, P., & Supraja, N. (2022) · Polymer Bulletin · doi:10.1007/s00289-021-04050-9 · Cited by 1

BF3-assisted insolubilization switching toward bilayer π-conjugated polymer film

Yoshino, Y., Nakabayashi, M., & Hayashi, S. (2023) · Reactive and Functional Polymers · doi:10.1016/j.reactfunctpolym.2023.105554 · Cited by 1

Synthesis of O-B ← N embedded molecules and studies on the B ← N cleavage-driven thermo- and solvatochromic properties

Gao, B., Zheng, X., Yang, L., Zhao, J., Tan, X., Jian, J., Luo, G., & Huang, J. (2024) · Tetrahedron Letters · doi:10.1016/j.tetlet.2024.154908 · Cited by 1

Development of π-Conjugated Polymer Complexes and Their Application to Organic Electronics

Kimoto, A. (2017) · KOBUNSHI RONBUNSHU · doi:10.1295/koron.2017-0025

Thiophenes, benzannulated forms, and analogs

Sadimenko, A. P. (2019) · Elsevier eBooks · doi:10.1016/b978-0-08-102860-5.00002-x

Comparison of excited states between thiophene-furan with thiophene-pyrrole oligomers: A computational study at the RI-ADC(2) level

Khatiwoda, N., & Panda, A. N. (2023) · Chemical Physics Letters · doi:10.1016/j.cplett.2023.140618

Synergy of machine learning and density functional theory calculations for predicting experimental Lewis base affinity and Lewis polybase binding atoms

Huynh, H., Le, K., Vu, L., Nguyen, T. T., Holcomb, M., Forli, S., & Phan, H. (2024) · Journal of Computational Chemistry · doi:10.1002/jcc.27329

A Thermally Populated Germylene‐Based Donor‐Acceptor Diradical

Zhao, Y., Zhang, Y., Wang, T., Pei, R., Zhao, Y. C., Xue, X., & Wang, X. (2024) · Angewandte Chemie · doi:10.1002/ange.202411180

Kwantumchemisch onderzoek naar anti-Kasha-fluorescentie

Veys, K. (2023) · Lirias

Lewis Acid‐Triggered Spatiotemporally Controllable Ring Opening in a Classic Rhodamine Featuring Φ = 95% Emission

Sun, Q., He, L., Wang, T., Cui, H., & Wang, X. (2026) · Small Science · doi:10.1002/smsc.202500522

Electrochromic near-infrared charge transfer and Lewis acid–base pairing for color tuning

Raj, A. M., Porlier, S., Malveau, C., & Skene, W. G. (2026) · Canadian Journal of Chemistry · doi:10.1139/cjc-2025-0185

Développement de polymères semi-conducteurs absorbant dans le proche infra-rouge pour des interfaces sans contact

Khelifi, W. (2019) · theses.fr (ABES) · doi:10.70675/842f202cz723ez417aza01fz08316267d3fc

P-doped semiconducting polymers : process optimization, characterization and investigation of air stability

Domschke, T. N. (2020) · theses.fr (ABES) · doi:10.70675/7b472987z3ff0z483dzae97z0b0a0505201f

Elaboration of rigid-rigid block copolymers based on polymers absorbing in the near-infrared for organic electronics

Idriss, H. (2020) · theses.fr (ABES) · doi:10.70675/b9d92fa4zf9dfz4e07z816ezadb2ac43d60e

Insights into structure-stability-property relationships in hybrid perovskites using solid-state NMR spectroscopy

Raval, P. (2022) · theses.fr (ABES) · doi:10.70675/0c43464dzc53bz4e64z87d3zba1d2a578713

Lewis Acid Adducts of Narrow Band Gap Conjugated Polymers

Welch, G. C., & Bazan, G. C. (2011) · Journal of the American Chemical Society · doi:10.1021/ja110968m · Cited by 231

Adjusting the energy levels and bandgaps of conjugated polymers via Lewis acid–base reactions

Li, Y., Meng, H., Li, Y., Pang, B., Luo, G., & Huang, J. (2018) · New Journal of Chemistry · doi:10.1039/c8nj04453h · Cited by 21

A Lewis acid-base chemistry approach towards narrow bandgap dye molecules

Huang, J., Li, Y., Wang, Y., Meng, H., Yan, D., Jiang, B., Wei, Z., & Zhan, C. (2018) · Dyes and Pigments · doi:10.1016/j.dyepig.2018.02.003 · Cited by 23

Unusual Doping of Donor–Acceptor-Type Conjugated Polymers Using Lewis Acids

Poverenov, E., Zamoshchik, N., Patra, A., Ridelman, Y., & Bendikov, M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501024n · Cited by 75

Post-synthesis from Lewis acid–base interaction: an alternative way to generate light and harvest triplet excitons

Liu, H., & Xie, G. (2022) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.18.83 · Cited by 6