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Isoreticular Metalation of Metal−Organic Frameworks
Abstract
Sequential covalent transformation and metalation were performed on (Zn(4)O)(3)(BDC-NH(2))(3)(BTB)(4) with maintenance of crystallinity and porosity. Reaction of (Zn(4)O)(3)(BDC-NH(2))(3)(BTB)(4) with 2-pyridinecarboxaldehyde in toluene at room temperature for 5 days resulted in the formation of the extended crystalline structure (Zn(4)O)(3)(BDC-C(6)H(5)N(2))(3)(BTB)(4), which possesses iminopyridine moieties covalently bound to the organic links of the framework. Subsequent reaction with PdCl(2)(CH(3)CN)(2) in CH(2)Cl(2) at room temperature for 12 h yielded the metalated metal-organic framework (Zn(4)O)(3)(BDC-C(6)H(5)N(2)PdCl(2))(3)(BTB)(4). Both functionalized materials retained high crystallinity and were permanently porous with high surface areas [3200 and 1700 m(2) g(-1) for (Zn(4)O)(3)(BDC-C(6)H(5)N(2))(3)(BTB)(4) and (Zn(4)O)(3)(BDC-C(6)H(5)N(2)PdCl(2))(3)(BTB)(4), respectively.].
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Citations
Cited by
Tailored crystalline microporous materials by post-synthesis modification
Valtchev, V., Majano, G., Mintova, S., & Pérez-Ramírez, J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35196j · Cited by 478
Metal–organic frameworks (MOFs): potential and challenges for capture and abatement of ammonia
Vikrant, K., Kumar, V., Kim, K.-H., & Kukkar, D. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta07847a · Cited by 299
Metadata
- Authors
- Doonan, C. J., Morris, W., Furukawa, H., & Yaghi, O. M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-06-17
- Volume
- 131
- Issue
- 27
- Pages
- 9492-9493
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2020353271
- Cited by
- 291
- References
- 0
- FWCI
- 19.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Doonan, C. J., Morris, W., Furukawa, H., & Yaghi, O. M. (2009). Isoreticular Metalation of Metal−Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/ja903251e
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