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Exceptional Stability and High Hydrogen Uptake in Hydrogen-Bonded Metal−Organic Cubes Possessing ACO and AST Zeolite-like Topologies
Open accessAbstract
Herein we detail a novel approach for targeting zeolite-like metal-organic frameworks (ZMOFs) that utilizes metal-organic cubes, which are regarded as double four-membered rings (d4Rs) and are composite building units (BUs) in traditional inorganic zeolites. Accordingly, we outline the successful implementation of this strategy by reporting two ZMOFs with ACO and AST zeolite-like topologies, which were constructed from d4R BUs exclusively held together by hydrogen bonds. Their porosity was evaluated, delineating high hydrogen uptake and exceptional stability for the two hydrogen-bonded materials.
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Cited by
Farha, O. K., Özgür Yazaydın, A., Eryazici, I., Malliakas, C. D., Hauser, B. G., Kanatzidis, M. G., Nguyen, S. T., Snurr, R. Q., & Hupp, J. T. (2010) · Nature Chemistry · doi:10.1038/nchem.834 · Cited by 1,741
A supermolecular building approach for the design and construction of metal–organic frameworks
Guillerm, V., Kim, D., Eubank, J. F., Luebke, R., Liu, X., Adil, K., Lah, M. S., & Eddaoudi, M. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00135d · Cited by 827
Self-citationZeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties
Eddaoudi, M., Sava, D. F., Eubank, J. F., Adil, K., & Guillerm, V. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00230j · Cited by 773
Self-citationHydrogen Storage in Metal-Organic Frameworks: A Review
Langmi, H. W., Ren, J., North, B., Mathe, M., & Bessarabov, D. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2013.10.190 · Cited by 461
Zheng, S.-T., Bu, J. T., Li, Y., Wu, T., Zuo, F., Feng, P., & Bu, X. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106903p · Cited by 373
Metadata
- Authors
- Sava, D. F., Kravtsov, V. C., Eckert, J., Eubank, J. F., Nouar, F., & Eddaoudi, M.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-07-09
- Volume
- 131
- Issue
- 30
- Pages
- 10394-10396
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1973200472
- Cited by
- 159
- References
- 0
- FWCI
- 9.19
- Type
- journal article
- Language
- en
- Open access
- gold
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- The paper
- Sava, D. F., Kravtsov, V. C., Eckert, J., Eubank, J. F., Nouar, F., & Eddaoudi, M. (2009). Exceptional Stability and High Hydrogen Uptake in Hydrogen-Bonded Metal−Organic Cubes Possessing ACO and AST Zeolite-like Topologies. Journal of the American Chemical Society. https://doi.org/10.1021/ja903287v
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