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Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture
Abstract
Multiferroic behavior in perovskite-related metal-organic frameworks of general formula [(CH(3))(2)NH(2)]M(HCOO)(3), where M = Mn, Fe, Co, and Ni, is reported. All four compounds exhibit paraelectric-antiferroelectric phase transition behavior in the temperature range 160-185 K (Mn: 185 K, Fe: 160 K; Co: 165 K; Ni: 180 K); this is associated with an order-disorder transition involving the hydrogen bonded dimethylammonium cations. On further cooling, the compounds become canted weak ferromagnets below 40 K. This research opens up a new class of multiferroics in which the electrical ordering is achieved by means of hydrogen bonding.
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Citations
Cited by
Ferroelectric Metal–Organic Frameworks
Zhang, W., & Xiong, R.-G. (2012) · Chemical Reviews · doi:10.1021/cr200174w · Cited by 1,378
Metal-free three-dimensional perovskite ferroelectrics
Ye, H.-Y., Tang, Y.-Y., Li, P.-F., Liao, W.-Q., Gao, J.-X., Hua, X.-N., Cai, H., Shi, P.-P., You, Y.-M., & Xiong, R.-G. (2018) · Science · doi:10.1126/science.aas9330 · Cited by 814
Tan, J. C., & Cheetham, A. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00163e · Cited by 762
Self-citationMetal–organic complex ferroelectrics
Hang, T., Zhang, W., Ye, H.-Y., & Xiong, R.-G. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00226g · Cited by 329
Metadata
- Authors
- Jain, P., Ramachandran, V., Clark, R. J., Zhou, H. D., Toby, B. H., Dalal, N. S., Kroto, H. W., & Cheetham, A. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-09-02
- Volume
- 131
- Issue
- 38
- Pages
- 13625-13627
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2059841912
- Cited by
- 798
- References
- 0
- FWCI
- 14.53
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture. https://app.cochat.ai/papers/10.1021/ja904156s
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- Jain, P., Ramachandran, V., Clark, R. J., Zhou, H. D., Toby, B. H., Dalal, N. S., Kroto, H. W., & Cheetham, A. K. (2009). Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture. Journal of the American Chemical Society. https://doi.org/10.1021/ja904156s
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