The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites
Abstract
Six prototype microporous metal-organic frameworks (MOFs) HKUST-1, MOF-505, MOF-508, MIL-53, MOF-5, and ZIF-8 with variable structures and porosities were examined for their acetylene storage, highlighting HKUST-1 as the highest acetylene storage material ever reported with an uptake of 201 cm(3)/g at 295 K and 1 atm. To locate the acetylene binding sites within HKUST-1, neutron powder diffraction studies on acetylene loaded HKUST-1 were carried out and have conclusively established the significant contribution of open Cu(2+) sites for acetylene storage by their strong preferred interactions with acetylene molecules. The binding properties of acetylene gas at different sites were further investigated by first-principles calculations.
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Cites
An Amine-Functionalized MIL-53 Metal−Organic Framework with Large Separation Power for CO 2 and CH 4
Couck, S., Denayer, J. F. M., Baron, G. V., Rémy, T., Gascon, J., & Kapteijn, F. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900555r · Cited by 988
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Kökçam-Demir, Ü., Goldman, A., Esrafili, L., Gharib, M., Morsali, A., Weingart, O., & Janiak, C. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00609e · Cited by 895
Mao, Y., Li, G., Guo, Y., Li, Z., Liang, C., Peng, X., & Lin, Z. (2017) · Nature Communications · doi:10.1038/ncomms14628 · Cited by 518
Zheng, S.-T., Bu, J. T., Li, Y., Wu, T., Zuo, F., Feng, P., & Bu, X. (2010) · Journal of the American Chemical Society · doi:10.1021/ja106903p · Cited by 373
Competitive I2 Sorption by Cu-BTC from Humid Gas Streams
Sava, D. F., Chapman, K. W., Rodriguez, M. A., Greathouse, J. A., Crozier, P. S., Zhao, H., Chupas, P. J., & Nenoff, T. M. (2013) · Chemistry of Materials · doi:10.1021/cm401762g · Cited by 363
Metadata
- Authors
- Xiang, S., Zhou, W., Gallegos, J. M., Liu, Y., & Chen, B.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-08-10
- Volume
- 131
- Issue
- 34
- Pages
- 12415-12419
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2077751077
- Cited by
- 576
- References
- 1
- FWCI
- 19.58
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xiang, S., Zhou, W., Gallegos, J. M., Liu, Y., & Chen, B. (2009). Exceptionally High Acetylene Uptake in a Microporous Metal−Organic Framework with Open Metal Sites. Journal of the American Chemical Society. https://doi.org/10.1021/ja904782h
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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