The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
Abstract
The mechanism of Ce(IV) water oxidation catalyzed by [Ru(tpy)(bpm)(OH(2))](2+) (tpy = 2,2':6',2''-terpyridine; bpm = 2,2'-bipyrimidine) and related single-site catalysts has been determined by a combination of mixing and stopped-flow experiments with spectrophotometric monitoring. The mechanism features O---O coupling by water attack on Ru(V)=O(3+) and three peroxidic intermediates that have been characterized by a combination of spectroscopy and DFT calculations.
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Citations
Cites
Density-functional thermochemistry. III. The role of exact exchange
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464913 · Cited by 103,767
Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Self-citation
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Reier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
Water-oxidation catalysis by manganese in a geochemical-like cycle
Hocking, R. K., Brimblecombe, R., Chang, L.-Y., Singh, A., Cheah, M. H., Glover, C., Casey, W. H., & Spiccia, L. (2011) · Nature Chemistry · doi:10.1038/nchem.1049 · Cited by 517
Intramolecular Proton Transfer Boosts Water Oxidation Catalyzed by a Ru Complex
Matheu, R., Ertem, M. Z., Benet-Buchholz, J., Coronado, E., Batista, V. S., Sala, X., & Llobet, A. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06541 · Cited by 308
Metadata
- Authors
- Concepcion, J. J., Tsai, M.-K., Muckerman, J. T., & Meyer, T. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-01-19
- Volume
- 132
- Issue
- 5
- Pages
- 1545-1557
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2053834882
- Cited by
- 482
- References
- 3
- FWCI
- 30.67
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
