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Double-Shelled Nanocapsules of V2O5-Based Composites as High-Performance Anode and Cathode Materials for Li Ion Batteries
Abstract
Double-shelled nanocapsules of V(2)O(5)-SnO(2) composites were chemically assembled via a one-pot solution method. These hollow nanocapsules are composed of a double-shelled V(2)O(5) matrix that includes a low weight ratio of SnO(2) (e.g., 10 or 15%). In these double shells, open-structured V(2)O(5) acts as not only a supporting matrix but also an active electrode component. The gap between the two shells and the hollow cavity provide sufficient space for volume variation during conversion reactions and lithium alloying/dealloying processes. As a promising anode electrode, this nanocomposite shows a large, reversible capacity of 947 mA h g(-1) at a rate of 250 mA g(-1) and retains a high capacity of 673 mA h g(-1) after 50 cycles. Even at a high rate of 2500 mA g(-1), the current nanocomposite electrode can still deliver a reversible capacity of 505 mA h g(-1). As a cathode electrode, our nanocomposite shows not only a high reversible capacity of approximately 250 mA h g(-1) but also good cycling and rate capability.
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Self-citation
Metadata
- Authors
- Liu, J., Xia, H., Xue, D., & Lu, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-08-10
- Volume
- 131
- Issue
- 34
- Pages
- 12086-12087
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2082318066
- Cited by
- 563
- References
- 0
- FWCI
- 32.21
- Type
- journal article
- Language
- en
- Open access
- closed
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