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Double-Shelled Nanocapsules of V2O5-Based Composites as High-Performance Anode and Cathode Materials for Li Ion Batteries

Liu, Jun, Xia, Hui, Xue, Dongfeng, Lu, Li·2009·Journal of the American Chemical Society

Abstract

Double-shelled nanocapsules of V(2)O(5)-SnO(2) composites were chemically assembled via a one-pot solution method. These hollow nanocapsules are composed of a double-shelled V(2)O(5) matrix that includes a low weight ratio of SnO(2) (e.g., 10 or 15%). In these double shells, open-structured V(2)O(5) acts as not only a supporting matrix but also an active electrode component. The gap between the two shells and the hollow cavity provide sufficient space for volume variation during conversion reactions and lithium alloying/dealloying processes. As a promising anode electrode, this nanocomposite shows a large, reversible capacity of 947 mA h g(-1) at a rate of 250 mA g(-1) and retains a high capacity of 673 mA h g(-1) after 50 cycles. Even at a high rate of 2500 mA g(-1), the current nanocomposite electrode can still deliver a reversible capacity of 505 mA h g(-1). As a cathode electrode, our nanocomposite shows not only a high reversible capacity of approximately 250 mA h g(-1) but also good cycling and rate capability.

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Authors
Liu, J., Xia, H., Xue, D., & Lu, L.
Venue
Journal of the American Chemical Society
Published
2009-08-10
Volume
131
Issue
34
Pages
12086-12087
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2082318066
Cited by
563
References
0
FWCI
32.21
Type
journal article
Language
en
Open access
closed

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