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Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material
Abstract
The electronic switching properties of the nanoporous spin crossover framework [Fe(NCS)(2)(bpbd)(2)] x x(guest), SCOF-2, can be rationally manipulated via sorption of a range of molecular guests (acetone, ethanol, methanol, propanol, 1-acetonitrile) into the 1-D channels of this material. Pronounced changes to the spin crossover properties are related directly to the steric and electronic influence of the individual guests: the degree of lattice cooperativity, as reflected in the abruptness of the transition and presence of hysteresis, is strongly influenced by the presence of cooperative host-guest interactions, and the temperature of the transition varies with guest polarity through a proposed electrostatic interaction.
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Cited by
Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
Ni, Z.-P., Liu, J.-L., Hoque, M. N., Liu, W., Li, J.-Y., Chen, Y.-C., & Tong, M.-L. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2016.12.002 · Cited by 448
Entangled Two-Dimensional Coordination Networks: A General Survey
Carlucci, L., Ciani, G., Proserpio, D. M., Mitina, T. G., & Blatov, V. A. (2014) · Chemical Reviews · doi:10.1021/cr500150m · Cited by 285
Janet, J. P., Chan, L., & Kulik, H. J. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b00170 · Cited by 200
Strategies and Software for Machine Learning Accelerated Discovery in Transition Metal Chemistry
Nandy, A., Duan, C., Janet, J. P., Gugler, S., & Kulik, H. J. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.8b04015 · Cited by 161
Seeing Is Believing: Experimental Spin States from Machine Learning Model Structure Predictions
Taylor, M. G., Yang, T., Lin, S., Nandy, A., Janet, J. P., Duan, C., & Kulik, H. J. (2020) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.0c01458 · Cited by 81
Metadata
- Authors
- Neville, S. M., Halder, G. J., Chapman, K. W., Duriska, M. B., Moubaraki, B., Murray, K. S., & Kepert, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-08-11
- Volume
- 131
- Issue
- 34
- Pages
- 12106-12108
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2044245133
- Cited by
- 215
- References
- 0
- FWCI
- 8.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Neville, S. M., Halder, G. J., Chapman, K. W., Duriska, M. B., Moubaraki, B., Murray, K. S., & Kepert, C. J. (2009). Guest Tunable Structure and Spin Crossover Properties in a Nanoporous Coordination Framework Material. Journal of the American Chemical Society. https://doi.org/10.1021/ja905360g
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