The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Synthesis and Hydrogen Storage Properties of Be12(OH)12(1,3,5-benzenetribenzoate)4
Abstract
The first crystalline beryllium-based metal-organic framework has been synthesized and found to exhibit an exceptional surface area useful for hydrogen storage. Reaction of 1,3,5-benzenetribenzoic acid (H(3)BTB) and beryllium nitrate in a mixture of DMSO, DMF, and water at 130 degrees C for 10 days affords the solvated form of Be(12)(OH)(12)(1,3,5-benzenetribenzoate)(4) (1). Its highly porous framework structure consists of unprecedented saddle-shaped [Be(12)(OH)(12)](12+) rings connected through tritopic BTB(3-) ligands to generate a 3,12 net. Compound 1 exhibits a BET surface area of 4030 m(2)/g, the highest value yet reported for any main group metal-organic framework or covalent organic framework. At 77 K, the H(2) adsorption data for 1 indicate a fully reversible uptake of 1.6 wt % at 1 bar, with an initial isosteric heat of adsorption of -5.5 kJ/mol. At pressures up to 100 bar, the data show the compound to serve as an exceptional hydrogen storage material, reaching a total uptake of 9.2 wt % and 44 g/L at 77 K and of 2.3 wt % and 11 g/L at 298 K. It is expected that reaction conditions similar to those reported here may enable the synthesis of a broad new family of beryllium-based frameworks with extremely high surface areas.
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Metadata
- Authors
- Sumida, K., Hill, M. R., Horike, S., Dailly, A., & Long, J. R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-10-02
- Volume
- 131
- Issue
- 42
- Pages
- 15120-15121
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1992930037
- Cited by
- 268
- References
- 23
- FWCI
- 17.98
- Type
- journal article
- Language
- en
- Open access
- closed
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