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High Yield, Large Scale Synthesis of Thiolate-Protected Ag7 Clusters
Abstract
We report a high yielding synthesis of truly monodisperse, thiolate-protected silver clusters via a rationally designed approach. The cluster composition was determined by electrospray ionization (ESI) mass spectrometry to be Ag(7)(DMSA)(4), where DMSA represents meso-2,3-dimercaptosuccinic acid. The Ag(7) thiolate clusters exhibit distinct optical properties. The approach developed in this work provides some insight into the cluster growth kinetics and may be extendable to the synthesis of other sized silver nanoclusters.
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Citations
Cited by
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Yang, H., Wang, Y., Huang, H., Gell, L., Lehtovaara, L., Malola, S., Häkkinen, H., & Zheng, N. (2013) · Nature Communications · doi:10.1038/ncomms3422 · Cited by 786
Wei, W., Lu, Y., Chen, W., & Chen, S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja109303z · Cited by 481
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Yuan, X., Luo, Z., Yu, Y., Yao, Q., & Xie, J. (2013) · Chemistry – An Asian Journal · doi:10.1002/asia.201201236 · Cited by 328
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Metadata
- Authors
- Wu, Z., Lanni, E., Chen, W., Bier, M. E., Ly, D., & Jin, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-11-03
- Volume
- 131
- Issue
- 46
- Pages
- 16672-16674
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1997136694
- Cited by
- 285
- References
- 0
- FWCI
- 10.69
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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