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Indene−C60Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells

He, Youjun, Chen, Hsiang-Yu, Hou, Jianhui, Li, Yongfang·2010·Journal of the American Chemical Society

Abstract

Polymer solar cells (PSCs) are commonly composed of a blend film of a conjugated polymer donor and a soluble C(60) derivative acceptor sandwiched between an ITO anode and a low-workfunction metal cathode. Poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) are the most widely used donor and acceptor materials, respectively. However, the low LUMO energy level of PCBM limits the open circuit voltage (V(oc)) of the P3HT-based PSCs to ca. 0.6 V. Here we synthesized a new soluble C(60) derivative, indene-C(60) bisadduct (ICBA), with a LUMO energy level 0.17 eV higher than that of PCBM. The PSC based on P3HT with ICBA as acceptor shows a higher V(oc) of 0.84 V and higher power conversion efficiency (PCE) of 5.44% under the illumination of AM1.5, 100 mW/cm(2), while the PSC based on P3HT/PCBM displays a V(oc) of 0.58 V and PCE of 3.88% under the same experimental conditions. The results indicate that ICBA is an alternative high-performance acceptor and could be widely used in high-performance PSCs.

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Metadata

Authors
He, Y., Chen, H.-Y., Hou, J., & Li, Y.
Venue
Journal of the American Chemical Society
Published
2010-02-03
Volume
132
Issue
4
Pages
1377-1382
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1979470200
Cited by
1,244
References
0
FWCI
99.18
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Indene−C60Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells. https://app.cochat.ai/papers/10.1021/ja908602j
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He, Y., Chen, H.-Y., Hou, J., & Li, Y. (2010). Indene−C60Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells. Journal of the American Chemical Society. https://doi.org/10.1021/ja908602j

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