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Unexpected CO2 Splitting Reactions To Form CO with N-Heterocyclic Carbenes as Organocatalysts and Aromatic Aldehydes as Oxygen Acceptors
Abstract
The catalytic reduction of carbon dioxide to carbon monoxide under mild conditions using aromatic aldehydes as reductants and NHCs as organocatalysts was developed. This carbon dioxide splitting reaction provides a new method for metal-free carbon dioxide reduction and steps forward in utilizing carbon dioxide as a renewable "green" source under mild conditions. On the other hand, this reaction also shows a new economical way to oxidize aromatic aldehydes under mild conditions with carbon dioxide and could be applied in pharmaceutical synthesis.
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Citations
Cited by
Sustainable conversion of carbon dioxide: the advent of organocatalysis
Fiorani, G., Guo, W., & Kleij, A. W. (2015) · Green Chemistry · doi:10.1039/c4gc01959h · Cited by 658
Berkefeld, A., Piers, W. E., & Parvez, M. (2010) · Journal of the American Chemical Society · doi:10.1021/ja105320c · Cited by 512
Catalysis with N‐Heterocyclic Carbenes under Oxidative Conditions
De Sarkar, S., Biswas, A., Samanta, R. C., & Studer, A. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201203707 · Cited by 503
Zhukhovitskiy, A. V., MacLeod, M. J., & Johnson, J. A. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00220 · Cited by 363
Fast CO2 Sequestration, Activation, and Catalytic Transformation Using N-Heterocyclic Olefins
Wang, Y.-B., Wang, Y.-M., Zhang, W.-Z., & Lu, X.-B. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405114e · Cited by 314
Metadata
- Authors
- Gu, L., & Zhang, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-12-29
- Volume
- 132
- Issue
- 3
- Pages
- 914-915
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2024563100
- Cited by
- 196
- References
- 0
- FWCI
- 12.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gu, L., & Zhang, Y. (2010). Unexpected CO2 Splitting Reactions To Form CO with N-Heterocyclic Carbenes as Organocatalysts and Aromatic Aldehydes as Oxygen Acceptors. Journal of the American Chemical Society. https://doi.org/10.1021/ja909038t
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
