The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
High Yield Access to Silylene RSiCl (R = PhC(N t Bu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene
Abstract
Two new approaches for synthesizing RSiCl, (R = PhC(NtBu)(2)) are reported by the reaction of RSiHCl(2) with bis-trimethyl silyl lithium amide and N-heterocyclic carbene respectively. In the former method silylene is produced in 90% yield. The silylene was treated with biphenyl alkyne to afford the disilacyclobutene system. This is a rare example of two five-coordinate silicon centers arranged adjacent to each other in a four-membered ring. Furthermore, we fluorinated the four-membered ring by trimethyltin fluoride to obtain the fluoro substituted disilacyclobutene.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Lee, C., Yang, W., & Parr, R. G. (1988) · Physical Review B · doi:10.1103/physrevb.37.785 · Cited by 100,874
Sheldrick, G. M. (2008) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767307043930 · Cited by 87,804
Weigend, F., & Ahlrichs, R. (2005) · Physical Chemistry Chemical Physics · doi:10.1039/b508541a · Cited by 30,598
A new mixing of Hartree–Fock and local density-functional theories
Becke, A. D. (1993) · The Journal of Chemical Physics · doi:10.1063/1.464304 · Cited by 16,515
Electronic structure calculations on workstation computers: The program system turbomole
Ahlrichs, R., Bär, M., Häser, M., Horn, H., & Kölmel, C. (1989) · Chemical Physics Letters · doi:10.1016/0009-2614(89)85118-8 · Cited by 8,433
Synthesis and Characterization of [PhC(N t Bu)2]SiCl: A Stable Monomeric Chlorosilylene
So, C., Roesky, H. W., Magull, J., & Oswald, R. B. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200600647 · Cited by 368
Self-citationScott, N. M., Dorta, R., Stevens, E. D., Correa, A., Cavallo, L., & Nolan, S. P. (2005) · Journal of the American Chemical Society · doi:10.1021/ja043249f · Cited by 288
Cited by
Asay, M., Jones, C., & Driess, M. (2011) · Chemical Reviews · doi:10.1021/cr100216y · Cited by 1,253
Metadata
- Authors
- Sen, S. S., Roesky, H. W., Stern, D., Henn, J., & Stalke, D.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-12-31
- Volume
- 132
- Issue
- 3
- Pages
- 1123-1126
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2058920598
- Cited by
- 320
- References
- 7
- FWCI
- 14.78
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
