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Cited by 937

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High and Selective CO2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores

An, Jihyun, Geib, Steven J., Rosi, Nathaniel L.·2010·Journal of the American Chemical Society
DOI 10.1021/ja909169x
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Abstract

The synthesis and structure of Co(2)(ad)(2)(CO(2)CH(3))(2) x 2 DMF x 0.5 H(2)O (bio-MOF-11) is described. Pyrimidine and amino groups of adeninate (ad) decorate the pores of the framework. The porosity of this material was studied, and its CO(2) and H(2) adsorption properties were evaluated. bio-MOF-11 exhibits a high heat of adsorption for CO(2) (approximately 45 kJ/mol), a high CO(2) capacity (approximately 6 mmol/g, 273 K), and exceptional selectivity for CO(2) over N(2) at 273 K (81:1) and 298 K (75:1).

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Metadata

Authors
An, J., Geib, S. J., & Rosi, N. L.
Venue
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Published
2009-12-14
Volume
132
Issue
1
Pages
38-39
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
DOI
10.1021/ja909169x
OpenAlex
W1980147427
Cited by
937
References
0
FWCI
44.35
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: High and Selective CO2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores. https://app.cochat.ai/papers/10.1021/ja909169x
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An, J., Geib, S. J., & Rosi, N. L. (2010). High and Selective CO2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores. Journal of the American Chemical Society. https://doi.org/10.1021/ja909169x

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