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Cited by 363

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Control over Catenation in Metal−Organic Frameworks via Rational Design of the Organic Building Block

Farha, Omar K., Malliakas, Christos D., Kanatzidis, Mercouri G., Hupp, Joseph T.·2010·Journal of the American Chemical Society

Abstract

Metal-organic frameworks (MOFs), a hybrid class of materials comprising inorganic nodes and organic struts, have potential application in many areas due to their high surface areas and uniform pores and channels. One of the key challenges to be overcome in MOF synthesis is the strong propensity for catenation (growth of multiple independent networks within a given crystal), as catenation reduces cavity sizes and diminishes porosity. Here we demonstrate that rational design of organic building blocks, which act as strut-impervious scaffolds, can be exploited to generate highly desired noncatenated materials in a controlled fashion.

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Crossref · 10.1021/ja909519e

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Metadata

Authors
Farha, O. K., Malliakas, C. D., Kanatzidis, M. G., & Hupp, J. T.
Venue
Journal of the American Chemical Society
Published
2009-12-29
Volume
132
Issue
3
Pages
950-952
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1970410293
Cited by
363
References
1
FWCI
21.97
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.