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Ammonia Borane Confined by a Metal−Organic Framework for Chemical Hydrogen Storage: Enhancing Kinetics and Eliminating Ammonia

Li, Zhongyue, Zhu, Guangshan, Lu, Gaoqing, Qiu, Shilun, Yao, Xiangdong·2010·Journal of the American Chemical Society

Abstract

A system involving ammonia borane (AB) confined in a metal-organic framework (JUC-32-Y) was synthesized. The hypothesis of nanoconfinement and metallic catalysis was tested and found to be effective for enhancing the hydrogen release kinetics and preventing the formation of ammonia. The AB in JUC-32-Y started to release hydrogen at a temperature as low as 50 degrees C. The peak temperature of decomposition decreased 30 degrees C (shifted to 84 degrees C). AB inside JUC-32-Y can release 8.2 wt % hydrogen in 3 min at 95 degrees C and 8.0 and 10.2 wt % hydrogen within 10 min at 85 degrees C.

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Authors
Li, Z., Zhu, G., Lu, G., Qiu, S., & Yao, X.
Venue
Journal of the American Chemical Society
Published
2010-01-19
Volume
132
Issue
5
Pages
1490-1491
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2043778532
Cited by
260
References
0
FWCI
16.06
Type
journal article
Language
en
Open access
closed

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