The DOI matches its Crossref record.
Ammonia Borane Confined by a Metal−Organic Framework for Chemical Hydrogen Storage: Enhancing Kinetics and Eliminating Ammonia
Abstract
A system involving ammonia borane (AB) confined in a metal-organic framework (JUC-32-Y) was synthesized. The hypothesis of nanoconfinement and metallic catalysis was tested and found to be effective for enhancing the hydrogen release kinetics and preventing the formation of ammonia. The AB in JUC-32-Y started to release hydrogen at a temperature as low as 50 degrees C. The peak temperature of decomposition decreased 30 degrees C (shifted to 84 degrees C). AB inside JUC-32-Y can release 8.2 wt % hydrogen in 3 min at 95 degrees C and 8.0 and 10.2 wt % hydrogen within 10 min at 85 degrees C.
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Citations
Cited by
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Yu, X., Tang, Z., Sun, D., Ouyang, L., & Zhu, M. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.03.001 · Cited by 716
Improvement of the kinetics of hydrogen release from ammonia borane confined in silica aerogel
Rueda, M., Sanz-Moral, L. M., Segovia, J. J., & Martín, Á. (2017) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2016.09.030 · Cited by 28
Metadata
- Authors
- Li, Z., Zhu, G., Lu, G., Qiu, S., & Yao, X.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-01-19
- Volume
- 132
- Issue
- 5
- Pages
- 1490-1491
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2043778532
- Cited by
- 260
- References
- 0
- FWCI
- 16.06
- Type
- journal article
- Language
- en
- Open access
- closed
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