The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Direct Synthesis of Intermetallic Platinum–Alloy Nanoparticles Highly Loaded on Carbon Supports for Efficient Electrocatalysis
Abstract
Compared to nanostructured platinum (Pt) catalysts, ordered Pt-based intermetallic nanoparticles supported on a carbon substrate exhibit much enhanced catalytic performance, especially in fuel cell electrocatalysis. However, direct synthesis of homogeneous intermetallic alloy nanocatalysts on carbonaceous supports with high loading is still challenging. Herein, we report a novel synthetic strategy to directly produce highly dispersed MPt alloy nanoparticles (M = Fe, Co, or Ni) on various carbon supports with high catalyst loading. Importantly, a unique bimetallic compound, composed of [M(bpy) 3 ] 2+ cation (bpy = 2,2′-bipyridine) and [PtCl 6 ] 2– anion, evenly decomposes on carbon surface and forms uniformly sized intermetallic nanoparticles with a nitrogen-doped carbon protection layer. The excellent oxygen reduction reaction (ORR) activity and stability of the representative reduced graphene oxide (rGO)-supported L1 0 -FePt catalyst (37 wt %-FePt/rGO), exhibiting 18.8 times higher specific activity than commercial Pt/C catalyst without degradation over 20 000 cycles, well demonstrate the effectiveness of our synthetic approach toward uniformly alloyed nanoparticles with high homogeneity.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
Jain, A., Ong, S. P., Hautier, G., Chen, W., Richards, W. D., Dacek, S., Cholia, S., Gunter, D., Skinner, D., Ceder, G., et al. (2013) · APL Materials · doi:10.1063/1.4812323 · Cited by 13,094
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
Chen, C., Kang, Y., Huo, Z., Zhu, Z., Huang, W., Xin, H. L., Snyder, J. D., Li, D., Herron, J. A., Mavrikakis, M., et al. (2014) · Science · doi:10.1126/science.1249061 · Cited by 2,765
Wang, D., Xin, H. L., Hovden, R., Wang, H., Yu, Y., Muller, D. A., DiSalvo, F. J., & Abruña, H. D. (2013) · Nature Materials · doi:10.1038/nmat3458 · Cited by 2,082
Platinum-Based Oxygen Reduction Electrocatalysts
Wu, J., & Yang, H. (2013) · Accounts of Chemical Research · doi:10.1021/ar300359w · Cited by 1,050
Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction
Chung, D. Y., Jun, S. W., Yoon, G., Kwon, S. G., Shin, D. Y., Seo, P., Yoo, J. M., Shin, H., Chung, Y.-H., Kim, H., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09653 · Cited by 677
Self-citationNew Approach to Fully Ordered fct-FePt Nanoparticles for Much Enhanced Electrocatalysis in Acid
Li, Q., Wu, L., Wu, G., Su, D., Lv, H., Zhang, S., Zhu, W., Casimir, A., Zhu, H., Mendoza-Garcia, A., et al. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b00320 · Cited by 460
Intermetallic Nanoparticles: Synthetic Control and Their Enhanced Electrocatalysis
Li, J., & Sun, S. (2019) · Accounts of Chemical Research · doi:10.1021/acs.accounts.9b00172 · Cited by 354
Yano, H., Kataoka, M., Yamashita, H., Uchida, H., & Watanabe, M. (2007) · Langmuir · doi:10.1021/la070078u · Cited by 284
Du, X. X., He, Y., Wang, X. X., & Wang, J. N. (2016) · Energy & Environmental Science · doi:10.1039/c6ee01204c · Cited by 209
Influence of Oxide on the Oxygen Reduction Reaction of Carbon-Supported Pt−Ni Alloy Nanoparticles
Jeon, T.-Y., Yoo, S. J., Cho, Y.-H., Lee, K.-S., Kang, S. H., & Sung, Y.-E. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp9076273 · Cited by 74
Self-citation
Cited by
Sulfur-anchoring synthesis of platinum intermetallic nanoparticle catalysts for fuel cells
Yang, C.-L., Wang, L.-N., Yin, P., Liu, J., Chen, M.-X., Yan, Q.-Q., Wang, Z.-S., Xu, S.-L., Chu, S.-Q., Cui, C., et al. (2021) · Science · doi:10.1126/science.abj9980 · Cited by 908
Small molecule-assisted synthesis of carbon supported platinum intermetallic fuel cell catalysts
Song, T.-W., Xu, C., Sheng, Z.-T., Yan, H.-K., Tong, L., Liu, J., Zeng, W.-J., Zuo, L.-J., Yin, P., Zuo, M., et al. (2022) · Nature Communications · doi:10.1038/s41467-022-34037-7 · Cited by 193
Yang, J., Hübner, R., Zhang, J., Wan, H., Zheng, Y., Wang, H., Qi, H., He, L., Li, Y., Dubale, A. A., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015679 · Cited by 166
Liu, M., Lu, B., Yang, G., Yuan, P., Xia, H., Wang, Y., Guo, K., Zhao, S., Liu, J., Yu, Y., et al. (2022) · Advanced Science · doi:10.1002/advs.202200147 · Cited by 65
Chen, Z., Hao, C., Yan, B., Chen, Q., Feng, H., Mao, X., Cen, J., Tian, Z. Q., Tsiakaras, P., & Shen, P. K. (2022) · Advanced Energy Materials · doi:10.1002/aenm.202201600 · Cited by 50
Metadata
- Authors
- Yoo, T. Y., Yoo, J. M., Sinha, A. K., Bootharaju, M. S., Jung, E., Lee, H. S., Lee, B.-H., Kim, J., Antink, W. H., Kim, Y. M., Lee, J., Lee, E., Lee, D. W., Cho, S.-P., Yoo, S. J., Sung, Y.-E., & Hyeon, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-07-27
- Volume
- 142
- Issue
- 33
- Pages
- 14190-14200
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3046218526
- Cited by
- 268
- References
- 10
- FWCI
- 7.18
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Direct Synthesis of Intermetallic Platinum–Alloy Nanoparticles Highly Loaded on Carbon Supports for Efficient Electrocatalysis. https://app.cochat.ai/papers/10.1021/jacs.0c05140
- The paper
- Yoo, T. Y., Yoo, J. M., Sinha, A. K., Bootharaju, M. S., Jung, E., Lee, H. S., Lee, B.-H., Kim, J., Antink, W. H., Kim, Y. M., Lee, J., Lee, E., Lee, D. W., Cho, S.-P., Yoo, S. J., Sung, Y.-E., & Hyeon, T. (2020). Direct Synthesis of Intermetallic Platinum–Alloy Nanoparticles Highly Loaded on Carbon Supports for Efficient Electrocatalysis. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c05140
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
