The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 Photoreduction via Rational Design of Coordination Spheres on Metal–Organic Frameworks
Abstract
The recombination of electron–hole pairs severely detracts from the efficiency of photocatalysts. This issue could be addressed in metal–organic frameworks (MOFs) through optimization of the charge-transfer kinetics via rational design of structures at atomic level. Herein, a pyrazolyl porphyrinic Ni-MOF (PCN-601), integrating light harvesters, active catalytic sites, and high surface areas, has been demonstrated as a superior and durable photocatalyst for visible-light-driven overall CO 2 reduction with H 2 O vapor at room temperature. Kinetic studies reveal that the robust coordination spheres of pyrazolyl groups and Ni-oxo clusters endow PCN-601 with proper energy band alignment and ultrafast ligand-to-node electron transfer. Consequently, the CO 2 -to-CH 4 production rate of PCN-601 far exceeds those of the analogous MOFs based on carboxylate porphyrin and the classic Pt/CdS photocatalyst by more than 3- and 20-fold, respectively. The reaction avoids the use of hole scavengers and proceeds in a gaseous phase which can take full advantage of the high gas uptake of MOFs. This work demonstrates that the rational design of coordination spheres in MOF structures not only reconciles the contradiction between reactivity and stability but also greatly promotes the interfacial charge transfer to achieve optimized kinetics, providing guidance for the design of highly efficient MOF photocatalysts.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Metal–Organic Framework Materials as Chemical Sensors
Kreno, L. E., Leong, K., Farha, O. K., Allendorf, M., Van Duyne, R. P., & Hupp, J. T. (2012) · Chemical Reviews · doi:10.1021/cr200324t · Cited by 7,136
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Self-citationLow, J., Yu, J., Jaroniec, M., Wageh, S., & Al‐Ghamdi, A. A. (2017) · Advanced Materials · doi:10.1002/adma.201601694 · Cited by 5,031
Algorithms and tools for high-throughput geometry-based analysis of crystalline porous materials
Willems, T. F., Rycroft, C. H., Kazi, M., Meza, J. C., & Haranczyk, M. (2012) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2011.08.020 · Cited by 1,925
Enhanced Photocatalytic CO2-Reduction Activity of Anatase TiO2 by Coexposed {001} and {101} Facets
Yu, J., Low, J., Xiao, W., Zhou, P., & Jaroniec, M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja5044787 · Cited by 1,905
Fu, Y., Sun, D., Chen, Y., Huang, R., Ding, Z., Fu, X., & Li, Z. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108357 · Cited by 1,741
Tu, W., Zhou, Y., & Zou, Z. (2014) · Advanced Materials · doi:10.1002/adma.201400087 · Cited by 1,635
Ran, J., Jaroniec, M., & Qiao, S. (2018) · Advanced Materials · doi:10.1002/adma.201704649 · Cited by 1,531
A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate
Dan-Hardi, M., Serre, C., Frot, T., Rozes, L., Maurin, G., Sanchez, C., & Férey, G. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903726m · Cited by 1,440
Cited by
Ma, X., Liu, H., Yang, W., Mao, G., Zheng, L., & Jiang, H.-L. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05032 · Cited by 445
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
Liu, J., Goetjen, T. A., Wang, Q., Knapp, J. G., Wasson, M. C., Yang, Y., Syed, Z. H., Delferro, M., Notestein, J. M., Farha, O. K., et al. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00968k · Cited by 386
Self-citationPorphyrins and phthalocyanines as biomimetic tools for photocatalytic H2production and CO2reduction
Nikoloudakis, E., López-Duarte, I., Charalambidis, G., Ladomenou, K., Ince, M., & Coutsolelos, A. G. (2022) · Chemical Society Reviews · doi:10.1039/d2cs00183g · Cited by 369
Wu, Q.-J., Liang, J., Huang, Y.-B., & Cao, R. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.2c00326 · Cited by 325
Self-citationDislocated Bilayer MOF Enables High‐Selectivity Photocatalytic Reduction of CO2 to CO
Liang, J., Yu, H., Shi, J., Li, B., Wu, L., & Wang, M. (2023) · Advanced Materials · doi:10.1002/adma.202209814 · Cited by 270
Metadata
- Authors
- Fang, Z.-B., Liu, T.-T., Liu, J., Jin, S., Wu, X.-P., Gong, X.-Q., Wang, K., Yin, Q., Liu, T.-F., Cao, R., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-06-21
- Volume
- 142
- Issue
- 28
- Pages
- 12515-12523
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3036059291
- Cited by
- 473
- References
- 48
- FWCI
- 13.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Fang, Z.-B., Liu, T.-T., Liu, J., Jin, S., Wu, X.-P., Gong, X.-Q., Wang, K., Yin, Q., Liu, T.-F., Cao, R., & Zhou, H.-C. (2020). Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO2 Photoreduction via Rational Design of Coordination Spheres on Metal–Organic Frameworks. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c05530
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