The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Photoinduction of Cu Single Atoms Decorated on UiO-66-NH2 for Enhanced Photocatalytic Reduction of CO2 to Liquid Fuels
Abstract
Photocatalytic reduction of CO 2 to value-added fuels is a promising route to reduce global warming and enhance energy supply. However, poor selectivity and low efficiency of catalysts are usually the limiting factor of their applicability. Herein, a photoinduction method was developed to achieve the formation of Cu single atoms on a UiO-66-NH 2 support (Cu SAs/UiO-66-NH 2 ) that could significantly boost the photoreduction of CO 2 to liquid fuels. Notably, the developed Cu SAs/UiO-66-NH 2 achieved the solar-driven conversion of CO 2 to methanol and ethanol with an evolution rate of 5.33 and 4.22 μmol h –1 g –1, respectively. These yields were much higher than those of pristine UiO-66-NH 2 and Cu nanoparticles/UiO-66-NH 2 composites. Theoretical calculations revealed that the introduction of the Cu SAs on the UiO-66-NH 2 greatly facilitates the conversion of CO 2 to CHO* and CO* intermediates, leading to excellent selectivity toward methanol and ethanol. This study provides new insights for designing high-performance catalyst for photocatalytic reduction of CO 2 at the atomic scale.
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
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The technological and economic prospects for CO2 utilization and removal
Hepburn, C., Adlen, E., Beddington, J., Carter, E. A., Fuss, S., Mac Dowell, N., Minx, J. C., Smith, P., & Williams, C. K. (2019) · Nature · doi:10.1038/s41586-019-1681-6 · Cited by 2,523
Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
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Self-citationAtomic cobalt on nitrogen-doped graphene for hydrogen generation
Fei, H., Dong, J., Arellano-Jiménez, M. J., Ye, G., Dong Kim, N., Samuel, E. L. G., Peng, Z., Zhu, Z., Qin, F., Bao, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms9668 · Cited by 1,621
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Cited by
Wang, H., Li, X., Zhao, X., Li, C., Song, X., Zhang, P., Huo, P., & Li, X. (2022) · Chinese Journal of Catalysis · doi:10.1016/s1872-2067(21)63910-4 · Cited by 826
Single-atom catalysts for photocatalytic energy conversion
Xue, Z.-H., Luan, D., Zhang, H., & (David) Lou, X. W. (2022) · Joule · doi:10.1016/j.joule.2021.12.011 · Cited by 567
Wang, W., Deng, C., Xie, S., Li, Y., Zhang, W., Sheng, H., Chen, C., & Zhao, J. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c00206 · Cited by 523
Self-citationZhang, Y., Zhao, J., Wang, H., Xiao, B., Zhang, W., Zhao, X., Lv, T., Thangamuthu, M., Zhang, J., Guo, Y., et al. (2022) · Nature Communications · doi:10.1038/s41467-021-27698-3 · Cited by 490
Self-citationConstruction and application of base-stable MOFs: a critical review
Wang, K., Li, Y., Xie, L.-H., Li, X., & Li, J.-R. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00891a · Cited by 462
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Metadata
- Authors
- Wang, G., He, C.-T., Huang, R., Mao, J., Wang, D., & Li, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-10-29
- Volume
- 142
- Issue
- 45
- Pages
- 19339-19345
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3096014954
- Cited by
- 712
- References
- 6
- FWCI
- 16.67
- Type
- journal article
- Language
- en
- Open access
- closed
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