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Cited by 712

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

Photoinduction of Cu Single Atoms Decorated on UiO-66-NH2 for Enhanced Photocatalytic Reduction of CO2 to Liquid Fuels

Wang, Gang, He, Chun-Ting, Huang, Rong, Mao, Junjie, Wang, Dingsheng, Li, Yadong·2020·Journal of the American Chemical Society

Abstract

Photocatalytic reduction of CO 2 to value-added fuels is a promising route to reduce global warming and enhance energy supply. However, poor selectivity and low efficiency of catalysts are usually the limiting factor of their applicability. Herein, a photoinduction method was developed to achieve the formation of Cu single atoms on a UiO-66-NH 2 support (Cu SAs/UiO-66-NH 2 ) that could significantly boost the photoreduction of CO 2 to liquid fuels. Notably, the developed Cu SAs/UiO-66-NH 2 achieved the solar-driven conversion of CO 2 to methanol and ethanol with an evolution rate of 5.33 and 4.22 μmol h –1 g –1, respectively. These yields were much higher than those of pristine UiO-66-NH 2 and Cu nanoparticles/UiO-66-NH 2 composites. Theoretical calculations revealed that the introduction of the Cu SAs on the UiO-66-NH 2 greatly facilitates the conversion of CO 2 to CHO* and CO* intermediates, leading to excellent selectivity toward methanol and ethanol. This study provides new insights for designing high-performance catalyst for photocatalytic reduction of CO 2 at the atomic scale.

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Metadata

Authors
Wang, G., He, C.-T., Huang, R., Mao, J., Wang, D., & Li, Y.
Venue
Journal of the American Chemical Society
Published
2020-10-29
Volume
142
Issue
45
Pages
19339-19345
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W3096014954
Cited by
712
References
6
FWCI
16.67
Type
journal article
Language
en
Open access
closed

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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