The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Solvation Structure Design for Aqueous Zn Metal Batteries
Open accessAbstract
Aqueous Zn batteries are promising energy storage devices for large-scale energy-storage due to low cost and high energy density. However, their lifespan is limited by the water decomposition and Zn dendrite growth. Here, we suppress water reduction and Zn dendrite growth in dilute aqueous electrolyte by adding dimethyl sulfoxide (DMSO) into ZnCl 2 –H 2 O, in which DMSO replaces the H 2 O in Zn 2+ solvation sheath due to a higher Gutmann donor number (29.8) of DMSO than that (18) of H 2 O. The preferential solvation of DMSO with Zn 2+ and strong H 2 O–DMSO interaction inhibit the decomposition of solvated H 2 O. In addition, the decomposition of solvated DMSO forms Zn 12 (SO 4 ) 3 Cl 3 (OH) 15 ·5H 2 O, ZnSO 3, and ZnS enriched-solid electrolyte interphase (SEI) preventing Zn dendrite and further suppressing water decomposition. The ZnCl 2 –H 2 O–DMSO electrolyte enables Zn anodes in Zn||Ti half-cell to achieve a high average Coulombic efficiency of 99.5% for 400 cycles (400 h), and the Zn||MnO 2 full cell with a low capacity ratio of Zn:MnO 2 at 2:1 to deliver a high energy density of 212 Wh/kg (based on both cathode and anode) and maitain 95.3% of the capacity over 500 cycles at 8 C.
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Citations
Cites
Aqueous Batteries Operated at −50 °C
Nian, Q., Wang, J., Liu, S., Sun, T., Zheng, S., Zhang, Y., Tao, Z., & Chen, J. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908913 · Cited by 426
Cited by
A non-flammable hydrous organic electrolyte for sustainable zinc batteries
Han, D., Cui, C., Zhang, K., Wang, Z., Gao, J., Guo, Y., Zhang, Z., Wu, S., Yin, L., Weng, Z., et al. (2021) · Nature Sustainability · doi:10.1038/s41893-021-00800-9 · Cited by 685
Emerging Era of Electrolyte Solvation Structure and Interfacial Model in Batteries
Cheng, H., Sun, Q., Li, L., Zou, Y., Wang, Y., Cai, T., Zhao, F., Liu, G., Ma, Z., Wahyudi, W., et al. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.1c02425 · Cited by 640
Self-citationYuan, L., Hao, J., Kao, C.-C., Wu, C., Liu, H.-K., Dou, S.-X., & Qiao, S.-Z. (2021) · Energy & Environmental Science · doi:10.1039/d1ee02021h · Cited by 628
Li, M., Li, Z., Wang, X., Meng, J., Liu, X., Wu, B., Han, C., & Mai, L. (2021) · Energy & Environmental Science · doi:10.1039/d1ee00030f · Cited by 559
Zn-based batteries for sustainable energy storage: strategies and mechanisms
Tang, L., Peng, H., Kang, J., Chen, H., Zhang, M., Liu, Y., Kim, D. H., Liu, Y., & Lin, Z. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00295k · Cited by 548
Metadata
- Authors
- Cao, L., Li, D., Hu, E., Xu, J., Deng, T., Ma, L., Wang, Y., Yang, X.-Q., & Wang, C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-12-08
- Volume
- 142
- Issue
- 51
- Pages
- 21404-21409
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3111560045
- Cited by
- 1,392
- References
- 1
- FWCI
- 52.49
- Type
- journal article
- Language
- en
- Open access
- green
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