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Photosensitizing Metal–Organic Framework Enabling Visible-Light-Driven Proton Reduction by a Wells–Dawson-Type Polyoxometalate
Abstract
A simple and effective charge-assisted self-assembly process was developed to encapsulate a noble-metal-free polyoxometalate (POM) inside a porous and phosphorescent metal-organic framework (MOF) built from [Ru(bpy)3](2+)-derived dicarboxylate ligands and Zr6(μ3-O)4(μ3-OH)4 secondary building units. Hierarchical organization of photosensitizing and catalytic proton reduction components in such a POM@MOF assembly enables fast multielectron injection from the photoactive framework to the encapsulated redox-active POMs upon photoexcitation, leading to efficient visible-light-driven hydrogen production. Such a modular and tunable synthetic strategy should be applicable to the design of other multifunctional MOF materials with potential in many applications.
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Cited by
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Li, X., Yang, X., Xue, H., Pang, H., & Xu, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2020.100027 · Cited by 706
Photocatalytic Cr(VI) reduction in metal-organic frameworks: A mini-review
Wang, C.-C., Du, X.-D., Li, J., Guo, X.-X., Wang, P., & Zhang, J. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.030 · Cited by 659
Self-citationZhao, S.-N., Song, X.-Z., Song, S.-Y., & Zhang, H.-J. (2017) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.02.010 · Cited by 336
Kobina Sam, D., Kobina Sam, E., & Lv, X. (2020) · ChemElectroChem · doi:10.1002/celc.202000829 · Cited by 89
Metadata
- Authors
- Zhang, Z.-M., Zhang, T., Wang, C., Lin, Z., Long, L.-S., & Lin, W.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-02-27
- Volume
- 137
- Issue
- 9
- Pages
- 3197-3200
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2015122610
- Cited by
- 436
- References
- 0
- FWCI
- 21.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Photosensitizing Metal–Organic Framework Enabling Visible-Light-Driven Proton Reduction by a Wells–Dawson-Type Polyoxometalate. https://app.cochat.ai/papers/10.1021/jacs.5b00075
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- Zhang, Z.-M., Zhang, T., Wang, C., Lin, Z., Long, L.-S., & Lin, W. (2015). Photosensitizing Metal–Organic Framework Enabling Visible-Light-Driven Proton Reduction by a Wells–Dawson-Type Polyoxometalate. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b00075
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