The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
A New Molybdenum Nitride Catalyst with Rhombohedral MoS2 Structure for Hydrogenation Applications
Abstract
Nitrogen-rich transition-metal nitrides hold great promise to be the next-generation catalysts for clean and renewable energy applications. However, incorporation of nitrogen into the crystalline lattices of transition metals is thermodynamically unfavorable at atmospheric pressure; most of the known transition metal nitrides are nitrogen-deficient with molar ratios of N:metal less than a unity. In this work, we have formulated a high-pressure route for the synthesis of a nitrogen-rich molybdenum nitride through a solid-state ion-exchange reaction. The newly discovered nitride, 3R-MoN2, adopts a rhombohedral R3m structure, isotypic with MoS2. This new nitride exhibits catalytic activities that are three times more active than the traditional catalyst MoS2 for the hydrodesulfurization of dibenzothiophene and more than twice as high in the selectivity to hydrogenation. The nitride is also catalytically active in sour methanation of syngas with >80% CO and H2 conversion at 723 K. Our formulated route for the synthesis of 3R-MoN2 is at a moderate pressure of 3.5 GPa and, thus, is feasible for industrial-scale catalyst production.
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Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Enhanced catalytic activity in strained chemically exfoliated WS2 nanosheets for hydrogen evolution
Voiry, D., Yamaguchi, H., Li, J., Silva, R., Alves, D. C. B., Fujita, T., Chen, M., Asefa, T., Shenoy, V. B., Eda, G., et al. (2013) · Nature Materials · doi:10.1038/nmat3700 · Cited by 2,641
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
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Cited by
Chen, Z., Song, Y., Cai, J., Zheng, X., Han, D., Wu, Y., Zang, Y., Niu, S., Liu, Y., Zhu, J., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201801834 · Cited by 1,075
Transition metal nitrides for electrochemical energy applications
Wang, H., Li, J., Li, K., Lin, Y., Chen, J., Gao, L., Nicolosi, V., Xiao, X., & Lee, J.-M. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00415d · Cited by 983
Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution
Chen, Z., Duan, X., Wei, W., Wang, S., & Ni, B.-J. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta03220g · Cited by 753
Self-citationLim, K. R. G., Handoko, A. D., Nemani, S. K., Wyatt, B., Jiang, H.-Y., Tang, J., Anasori, B., & Seh, Z. W. (2020) · ACS Nano · doi:10.1021/acsnano.0c05482 · Cited by 585
Jin, H., Wang, X., Tang, C., Vasileff, A., Li, L., Slattery, A., & Qiao, S. (2021) · Advanced Materials · doi:10.1002/adma.202007508 · Cited by 538
Metadata
- Authors
- Wang, S., Ge, H., Sun, S., Zhang, J., Liu, F., Wen, X., Yu, X., Wang, L., Zhang, Y., Xu, H., Neuefeind, J. C., Qin, Z., Chen, C., Jin, C., Li, Y., He, D., & Zhao, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-01
- Volume
- 137
- Issue
- 14
- Pages
- 4815-4822
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2329096115
- Cited by
- 235
- References
- 4
- FWCI
- 27.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, S., Ge, H., Sun, S., Zhang, J., Liu, F., Wen, X., Yu, X., Wang, L., Zhang, Y., Xu, H., Neuefeind, J. C., Qin, Z., Chen, C., Jin, C., Li, Y., He, D., & Zhao, Y. (2015). A New Molybdenum Nitride Catalyst with Rhombohedral MoS2 Structure for Hydrogenation Applications. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b01446
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