The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Decarboxylative Fluorination of Aliphatic Carboxylic Acids via Photoredox Catalysis
Open accessAbstract
The direct conversion of aliphatic carboxylic acids to the corresponding alkyl fluorides has been achieved via visible light-promoted photoredox catalysis. This operationally simple, redox-neutral fluorination method is amenable to a wide variety of carboxylic acids. Photon-induced oxidation of carboxylates leads to the formation of carboxyl radicals, which upon rapid CO2-extrusion and F(•) transfer from a fluorinating reagent yield the desired fluoroalkanes with high efficiency. Experimental evidence indicates that an oxidative quenching pathway is operable in this broadly applicable fluorination protocol.
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Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
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Cited by
Photoredox Catalysis in Organic Chemistry
Shaw, M. H., Twilton, J., & MacMillan, D. W. C. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01449 · Cited by 3,186
Self-citationMetallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis
Chan, A. Y., Perry, I. B., Bissonnette, N. B., Buksh, B. F., Edwards, G. A., Frye, L. I., Garry, O. L., Lavagnino, M. N., Li, B. X., Liang, Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00383 · Cited by 1,754
Self-citationDecarboxylative reactions with and without light – a comparison
Schwarz, J., & König, B. (2018) · Green Chemistry · doi:10.1039/c7gc02949g · Cited by 431
Photocatalysis in the Life Science Industry
Candish, L., Collins, K. D., Cook, G. C., Douglas, J. J., Gómez-Suárez, A., Jolit, A., & Keess, S. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00416 · Cited by 428
Zhou, Q., Guo, W., Ding, W., Wu, X., Chen, X., Lu, L., & Xiao, W. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201504559 · Cited by 326
Metadata
- Authors
- Ventre, S., Petronijevic, F. R., & MacMillan, D. W. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-04-27
- Volume
- 137
- Issue
- 17
- Pages
- 5654-5657
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2315095124
- Cited by
- 390
- References
- 1
- FWCI
- 23.97
- Type
- journal article
- Language
- en
- Open access
- green
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