The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior
Open accessAbstract
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual geometry as a source of magnetically anisotropic ground state. Here we report a cobalt(II) cage complex with a trigonal prism geometry showing single ion magnet behavior with very high Orbach relaxation barrier of 152 cm(-1). This, to our knowledge, is the largest reported relaxation barrier for a cobalt-based mononuclear SMM. The trigonal prismatic coordination provided by the macrocyclic ligand gives intrinsically more stable molecular species than previously reported SMMs, thus making this type of cage complexes more amendable to possible functionalization that will boost their magnetic anisotropy even further.
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Self-citationChilton, N. F., Anderson, R. P., Turner, L. D., Soncini, A., & Murray, K. S. (2013) · Journal of Computational Chemistry · doi:10.1002/jcc.23234 · Cited by 2,066
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Cited by
The role of anharmonic phonons in under-barrier spin relaxation of single molecule magnets
Lunghi, A., Totti, F., Sessoli, R., & Sanvito, S. (2017) · Nature Communications · doi:10.1038/ncomms14620 · Cited by 458
Metadata
- Authors
- Novikov, V. V., Pavlov, A. A., Nelyubina, Y. V., Boulon, M.-E., Varzatskii, O. A., Voloshin, Y. Z., & Winpenny, R. E. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-07-28
- Volume
- 137
- Issue
- 31
- Pages
- 9792-9795
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2414402924
- Cited by
- 344
- References
- 22
- FWCI
- 13.78
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Novikov, V. V., Pavlov, A. A., Nelyubina, Y. V., Boulon, M.-E., Varzatskii, O. A., Voloshin, Y. Z., & Winpenny, R. E. P. (2015). A Trigonal Prismatic Mononuclear Cobalt(II) Complex Showing Single-Molecule Magnet Behavior. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b05739
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