The DOI matches its Crossref record.
Single-Atom Pd1/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene
Abstract
We reported that atomically dispersed Pd on graphene can be fabricated using the atomic layer deposition technique. Aberration-corrected high-angle annular dark-field scanning transmission electron microscopy and X-ray absorption fine structure spectroscopy both confirmed that isolated Pd single atoms dominantly existed on the graphene support. In selective hydrogenation of 1,3-butadiene, the single-atom Pd1/graphene catalyst showed about 100% butenes selectivity at 95% conversion at a mild reaction condition of about 50 °C, which is likely due to the changes of 1,3-butadiene adsorption mode and enhanced steric effect on the isolated Pd atoms. More importantly, excellent durability against deactivation via either aggregation of metal atoms or carbonaceous deposits during a total 100 h of reaction time on stream was achieved. Therefore, the single-atom catalysts may open up more opportunities to optimize the activity, selectivity, and durability in selective hydrogenation reactions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Liu, D., Li, X., Chen, S., Yan, H., Wang, C., Wu, C., Haleem, Y. A., Duan, S., Lu, J., Ge, B., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0402-6 · Cited by 1,166
Self-citationTuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst
Choi, C. H., Kim, M., Kwon, H. C., Cho, S. J., Yun, S., Kim, H.-T., Mayrhofer, K. J. J., Kim, H., & Choi, M. (2016) · Nature Communications · doi:10.1038/ncomms10922 · Cited by 849
Single atom electrocatalysts supported on graphene or graphene-like carbons
Fei, H., Dong, J., Chen, D., Hu, T., Duan, X., Shakir, I., Huang, Y., & Duan, X. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00422j · Cited by 673
Zhang, C., Sha, J., Fei, H., Liu, M., Yazdi, S., Zhang, J., Zhong, Q., Zou, X., Zhao, N., Yu, H., et al. (2017) · ACS Nano · doi:10.1021/acsnano.7b02148 · Cited by 545
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Metadata
- Authors
- Yan, H., Cheng, H., Yi, H., Lin, Y., Yao, T., Wang, C., Li, J., Wei, S., & Lu, J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-17
- Volume
- 137
- Issue
- 33
- Pages
- 10484-10487
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2340423559
- Cited by
- 1,091
- References
- 0
- FWCI
- 34.46
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Single-Atom Pd1/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene. https://app.cochat.ai/papers/10.1021/jacs.5b06485
- The paper
- Yan, H., Cheng, H., Yi, H., Lin, Y., Yao, T., Wang, C., Li, J., Wei, S., & Lu, J. (2015). Single-Atom Pd1/Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b06485
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
