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Cited by 271

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Selective Catalytic Hydrogenation of Heteroarenes with N-Graphene-Modified Cobalt Nanoparticles (Co3O4–Co/NGr@α-Al2O3)

Chen, Feng, Surkus, Annette-Enrica, He, Lin, Pohl, Marga-Martina, Radnik, Jörg, Topf, Christoph, Junge, Kathrin, Beller, Matthias·2015·Journal of the American Chemical Society

Abstract

Cobalt oxide/cobalt-based nanoparticles featuring a core-shell structure and nitrogen-doped graphene layers on alumina are obtained by pyrolysis of Co(OAc)2/phenanthroline. The resulting core-shell material (Co3O4-Co/NGr@α-Al2O3) was successfully applied in the catalytic hydrogenation of a variety of N-heteroarenes including quinolines, acridines, benzo[h], and 1,5-naphthyridine as well as unprotected indoles. The peculiar structure of the novel heterogeneous catalyst enables activation of molecular hydrogen at comparably low temperature. Both high activity and selectivity were achieved in these hydrogenation processes, to give important building blocks for bioactive compounds as well as the pharmaceutical industry.

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Metadata

Authors
Chen, F., Surkus, A.-E., He, L., Pohl, M.-M., Radnik, J., Topf, C., Junge, K., & Beller, M.
Venue
Journal of the American Chemical Society
Published
2015-09-03
Volume
137
Issue
36
Pages
11718-11724
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2238889153
Cited by
271
References
1
FWCI
13.64
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Selective Catalytic Hydrogenation of Heteroarenes with N-Graphene-Modified Cobalt Nanoparticles (Co3O4–Co/NGr@α-Al2O3). https://app.cochat.ai/papers/10.1021/jacs.5b06496
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Chen, F., Surkus, A.-E., He, L., Pohl, M.-M., Radnik, J., Topf, C., Junge, K., & Beller, M. (2015). Selective Catalytic Hydrogenation of Heteroarenes with N-Graphene-Modified Cobalt Nanoparticles (Co3O4–Co/NGr@α-Al2O3). Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b06496

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.