The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation
Abstract
A series of bimetallic complexes pairing zero-valent nickel with group 13 M(III) ions is reported. Stronger Ni→M(III) dative bonds that render Ni more electron-deficient are seen for larger ions (In > Ga > Al). The larger Ga and In ions stabilize rare, nonclassical Ni-H2 adducts that catalyze olefin hydrogenation. In contrast, neither the Ni-Al complex nor a single nickel center enables H2 binding or olefin hydrogenation. By comparison of the structures, redox properties, and catalytic activities of the Ni-M series, the electronic and steric effects of the supporting metal ion are elucidated.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Pearson, R. G. (1963) · Journal of the American Chemical Society · doi:10.1021/ja00905a001 · Cited by 10,475
Cited by
Metal–Metal Bonds in Catalysis
Powers, I. G., & Uyeda, C. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b02692 · Cited by 369
Metadata
- Authors
- Cammarota, R. C., & Lu, C. C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-24
- Volume
- 137
- Issue
- 39
- Pages
- 12486-12489
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2269503844
- Cited by
- 248
- References
- 2
- FWCI
- 10.19
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation. https://app.cochat.ai/papers/10.1021/jacs.5b08313
- The paper
- Cammarota, R. C., & Lu, C. C. (2015). Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b08313
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
