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Pyrazolate-Based Porphyrinic Metal–Organic Framework with Extraordinary Base-Resistance
Abstract
Guided by a top-down topological analysis, a metal-organic framework (MOF) constructed by pyrazolate-based porphyrinic ligand, namely, PCN-601, has been rationally designed and synthesized, and it exhibits excellent stability in alkali solutions. It is, to the best of our knowledge, the first identified MOF that can retain its crystallinity and porosity in saturated sodium hydroxide solution (∼ 20 mol/L) at room temperature and 100 °C. This almost pushes base-resistance of porphyrinic MOFs (even if MOFs) to the limit in aqueous media and greatly extends the range of their potential applications. In this work, we also tried to interpret the stability of PCN-601 from both thermodynamic and kinetic perspectives.
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Cited by
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Self-citationLuminescent sensors based on metal-organic frameworks
Zhang, Y., Yuan, S., Day, G., Wang, X., Yang, X., & Zhou, H.-C. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.06.007 · Cited by 1,255
Self-citationApplications of water stable metal–organic frameworks
Wang, C., Liu, X., Keser Demir, N., Chen, J. P., & Li, K. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00362a · Cited by 1,249
Pristine Metal–Organic Frameworks and their Composites for Energy Storage and Conversion
Liang, Z., Qu, C., Guo, W., Zou, R., & Xu, Q. (2018) · Advanced Materials · doi:10.1002/adma.201702891 · Cited by 787
Luo, F., Yan, C., Dang, L., Krishna, R., Zhou, W., Wu, H., Dong, X., Han, Y., Hu, T.-L., O’Keeffe, M., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b02030 · Cited by 601
Metadata
- Authors
- Wang, K., Lv, X.-L., Feng, D., Li, J., Chen, S., Sun, J., Song, L., Xie, Y., Li, J.-R., & Zhou, H.-C.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-01-13
- Volume
- 138
- Issue
- 3
- Pages
- 914-919
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2239476714
- Cited by
- 419
- References
- 0
- FWCI
- 12.40
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, K., Lv, X.-L., Feng, D., Li, J., Chen, S., Sun, J., Song, L., Xie, Y., Li, J.-R., & Zhou, H.-C. (2016). Pyrazolate-Based Porphyrinic Metal–Organic Framework with Extraordinary Base-Resistance. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b10881
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