The DOI matches its Crossref record; 25 of the 25 references it cites were found in a registry or an index.
Layered Perovskite Oxychloride Bi4NbO8Cl: A Stable Visible Light Responsive Photocatalyst for Water Splitting
Abstract
Mixed anion compounds are expected to be a photocatalyst for visible light-induced water splitting, but the available materials have been almost limited to oxynitrides. Here, we show that an oxychrolide Bi4NbO8Cl, a single layer Sillen-Aurivillius perovskite, is a stable and efficient O2-evolving photocatalyst under visible light, enabling a Z-scheme overall water splitting by coupling with a H2-evolving photocatalyst (Rh-doped SrTiO3). It is found that the valence band maximum of Bi4NbO8Cl is unusually high owing to highly dispersive O-2p orbitals (not Cl-3p orbitals), affording the narrow band gap and possibly the stability against water oxidation. This study suggests that a family of Sillen-Aurivillius perovskite oxyhalides is a promising system to allow a versatile band level tuning for establishing efficient and stable water-splitting under visible light.
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Heterogeneous photocatalyst materials for water splitting
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Photocatalyst releasing hydrogen from water
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Inorganic Materials as Catalysts for Photochemical Splitting of Water
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New Non-Oxide Photocatalysts Designed for Overall Water Splitting under Visible Light
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Hydrogen Production by Molecular Photocatalysis
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Self-citationStudy of the electronic structure and photocatalytic activity of the BiOCl photocatalyst
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The Many “Facets” of Halide Ions in the Chemistry of Colloidal Inorganic Nanocrystals
Ghosh, S., & Manna, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00158 · Cited by 325
Use of metamodels for rapid discovery of narrow bandgap oxide photocatalysts
Mai, H., Le, T. C., Hisatomi, T., Chen, D., Domen, K., Winkler, D. A., & Caruso, R. A. (2021) · iScience · doi:10.1016/j.isci.2021.103068 · Cited by 32
Metadata
- Authors
- Fujito, H., Kunioku, H., Kato, D., Suzuki, H., Higashi, M., Kageyama, H., & Abe, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-02-15
- Volume
- 138
- Issue
- 7
- Pages
- 2082-2085
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2280091859
- Cited by
- 445
- References
- 25
- FWCI
- 13.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- Fujito, H., Kunioku, H., Kato, D., Suzuki, H., Higashi, M., Kageyama, H., & Abe, R. (2016). Layered Perovskite Oxychloride Bi4NbO8Cl: A Stable Visible Light Responsive Photocatalyst for Water Splitting. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b11191
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