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Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies
Open accessAbstract
Anisotropic colloidal quasi-two-dimensional nanoplates (NPLs) hold great promise as functional materials due to their combination of low dimensional optoelectronic properties and versatility through colloidal synthesis. Recently, lead-halide perovskites have emerged as important optoelectronic materials with excellent efficiencies in photovoltaic and light-emitting applications. Here we report the synthesis of quantum confined all inorganic cesium lead halide nanoplates in the perovskite crystal structure that are also highly luminescent (PLQY 84%). The controllable self-assembly of nanoplates either into stacked columnar phases or crystallographic-oriented thin-sheet structures is demonstrated. The broad accessible emission range, high native quantum yields, and ease of self-assembly make perovskite NPLs an ideal platform for fundamental optoelectronic studies and the investigation of future devices.
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Cites
Akkerman, Q. A., D’Innocenzo, V., Accornero, S., Scarpellini, A., Petrozza, A., Prato, M., & Manna, L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05602 · Cited by 2,197
Cited by
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
Akkerman, Q. A., Rainò, G., Kovalenko, M. V., & Manna, L. (2018) · Nature Materials · doi:10.1038/s41563-018-0018-4 · Cited by 2,287
High Defect Tolerance in Lead Halide Perovskite CsPbBr3
Kang, J., & Wang, L.-W. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02800 · Cited by 1,305
Fu, Y., Zhu, H., Chen, J., Hautzinger, M. P., Zhu, X.-Y., & Jin, S. (2019) · Nature Reviews Materials · doi:10.1038/s41578-019-0080-9 · Cited by 934
Zou, S., Liu, Y., Li, J., Liu, C., Feng, R., Jiang, F., Li, Y., Song, J., Zeng, H., Hong, M., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b04000 · Cited by 854
Strongly emissive perovskite nanocrystal inks for high-voltage solar cells
Akkerman, Q. A., Gandini, M., Di Stasio, F., Rastogi, P., Palazon, F., Bertoni, G., Ball, J. M., Prato, M., Petrozza, A., & Manna, L. (2016) · Nature Energy · doi:10.1038/nenergy.2016.194 · Cited by 721
Metadata
- Authors
- Bekenstein, Y., Koscher, B. A., Eaton, S. W., Yang, P., & Alivisatos, A. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-12-17
- Volume
- 137
- Issue
- 51
- Pages
- 16008-16011
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2202937947
- Cited by
- 1,169
- References
- 1
- FWCI
- 60.62
- Type
- journal article
- Language
- en
- Open access
- green
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- Bekenstein, Y., Koscher, B. A., Eaton, S. W., Yang, P., & Alivisatos, A. P. (2015). Highly Luminescent Colloidal Nanoplates of Perovskite Cesium Lead Halide and Their Oriented Assemblies. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b11199
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