The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides
Abstract
The strong metal-support interaction (SMSI) is of great importance for supported catalysts in heterogeneous catalysis. We report the first example of SMSI between Au nanoparticles (NPs) and hydroxyapatite (HAP), a nonoxide. The reversible encapsulation of Au NPs by HAP support, electron transfer, and changes in CO adsorption are identical to the classic SMSI except that the SMSI of Au/HAP occurred under oxidative condition; the opposite condition for the classical SMSI. The SMSI of Au/HAP not only enhanced the sintering resistance of Au NPs upon calcination but also improved their selectivity and reusability in liquid-phase reaction. It was found that the SMSI between Au and HAP is general and could be extended to other phosphate-supported Au systems such as Au/LaPO4. This new discovery may open a new way to design and develop highly stable supported Au catalysts with controllable activity and selectivity.
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Cites
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
Cited by
Ru/CeO2 Catalyst with Optimized CeO2 Support Morphology and Surface Facets for Propane Combustion
Wang, Z., Huang, Z., Brosnahan, J. T., Zhang, S., Guo, Y., Guo, Y., Wang, L., Wang, Y., & Zhan, W. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b01929 · Cited by 377
Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions
Zhang, Y., Liu, J., Qian, K., Jia, A., Li, D., Shi, L., Hu, J., Zhu, J., & Huang, W. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202101928 · Cited by 341
Self-citationStrong Metal Phosphide–Phosphate Support Interaction for Enhanced Non‐Noble Metal Catalysis
Chen, Z., Zeng, X., Li, X., Lv, Z., Li, J., & Zhang, Y. (2022) · Advanced Materials · doi:10.1002/adma.202106724 · Cited by 98
Liu, B., Zhu, Y., Sha, S., Ge, R., Cheng, C., Yin, J., Huang, Z., Dai, L., Li, S., & Li, W. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202408613 · Cited by 24
Metadata
- Authors
- Tang, H., Wei, J., Liu, F., Qiao, B., Pan, X., Li, L., Liu, J., Wang, J., & Zhang, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-12-28
- Volume
- 138
- Issue
- 1
- Pages
- 56-59
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2215738657
- Cited by
- 458
- References
- 1
- FWCI
- 11.19
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tang, H., Wei, J., Liu, F., Qiao, B., Pan, X., Li, L., Liu, J., Wang, J., & Zhang, T. (2016). Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b11306
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